Home
Class 12
CHEMISTRY
FeC(2)O(4) can decolorise acidified KMnO...

`FeC_(2)O_(4)` can decolorise acidified `KMnO_(4)` due to the oxidation of (a) _____and (b)____.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the decolorization of acidified KMnO4 by FeC2O4 (ferrous oxalate), we need to identify the species that are oxidized in the reaction. ### Step-by-Step Solution: 1. **Understanding the Reaction**: - Acidified KMnO4 is a strong oxidizing agent. In acidic conditions, it can oxidize various substances, including ferrous ions (Fe²⁺) and oxalate ions (C₂O₄²⁻). 2. **Identifying the Oxidized Species**: - The first species that gets oxidized is the **ferrous ion (Fe²⁺)**. It is oxidized to **ferric ion (Fe³⁺)**. - The second species that gets oxidized is the **oxalate ion (C₂O₄²⁻)**. It is oxidized to **carbon dioxide (CO₂)**. 3. **Writing the Half-Reactions**: - For the oxidation of ferrous ions: \[ \text{Fe}^{2+} \rightarrow \text{Fe}^{3+} + e^- \] - For the oxidation of oxalate ions: \[ \text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2 + 2e^- \] 4. **Combining the Half-Reactions**: - When these half-reactions are combined with the reduction half-reaction of KMnO4, we can see that the overall reaction leads to the decolorization of KMnO4 due to the reduction of MnO4⁻ to Mn²⁺. 5. **Conclusion**: - Therefore, the two species that are oxidized in the reaction are: - (a) **Ferrous ions (Fe²⁺)** - (b) **Oxalate ions (C₂O₄²⁻)** ### Final Answer: FeC₂O₄ can decolorize acidified KMnO₄ due to the oxidation of (a) **Ferrous ions (Fe²⁺)** and (b) **Oxalate ions (C₂O₄²⁻)**.
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (True And False )|20 Videos
  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Linked Comprehension)|2 Videos
  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Integer) (Naming And Terminology|15 Videos
  • P-BLOCK GROUP 18 ELEMENTS - THE INERT GASES

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 5.1 (Objective)|14 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise SUBJECTIVE TYPE|4 Videos

Similar Questions

Explore conceptually related problems

The color of KMnO_(4) is due to

The colour of KMnO_(4) is due to

Acidified KMnO_(4) can be decolourised by (a)_____.

Name the gas that decolourises acidified KMnO_4 solution.

Name the gas that can readily decolourise acidified KMnO_(4) solution:

By passing H_(2)S in acidified KMnO_(4) solution we get

One mole of KMnO_(4) is used for complete oxidation of FeSO_(4), FeC_(2)O_(4) and H_(2)C_(2)O_(4) respectively and separately. Pick up the correct statement.

A sample of FeSO_(4) and FeC_(2)O_(4) is dissolved in H_(2)SO_(4) . The complete oxidation of sample required 8/3 eq. of KMnO_(4) . After oxidation , the reaction mixture was reduced by Z. On again oxidation by KMnO_(4) required 5/3 eq. The mole ratio of FeSO_(4) and FeC_(2)O_(4) is

2mol FeSO_(4) in acid medium are oxidised by x mole of KMnO_(4) , where as 2 moleof FeC_(2)O_(4) in acid medium are oxidized by y mole of KMnO_(4) . The ratioof x and y is

KMnO_4 is acidified for redox titration by

CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Fill In The Blanks)
  1. Fe^(2+) gives blue coloue, called(a) with (b)white Fe^(2+) gives blue ...

    Text Solution

    |

  2. Ferric alum is the indicator in the titration of Ag^(o+) with SCN^(Θ)...

    Text Solution

    |

  3. FeC(2)O(4) can decolorise acidified KMnO(4) due to the oxidation of (...

    Text Solution

    |

  4. Acidified KMnO(4) can be decolourised by (a).

    Text Solution

    |

  5. Iron (II)sulphide gives foul smell of (a).

    Text Solution

    |

  6. AgBr is soluble in hypo forming (a) .

    Text Solution

    |

  7. NO(3)^(Θ) is detected by (a) when (b)is formed on the addition of FeS...

    Text Solution

    |

  8. CI^(Θ)is confirmed by (a) .

    Text Solution

    |

  9. Addition of one drop of HNO(3) in group (III) analysis is to (a) .

    Text Solution

    |

  10. Reagent that can detect any of Fe^(3+),Co^(2+) and Cu^(2+) is (a) .

    Text Solution

    |

  11. While testing borate, green edged flame is due so formation of (a) .

    Text Solution

    |

  12. When SO(2) is passed into suspention of CaSO(3) in water (a) is form...

    Text Solution

    |

  13. Alkaline Noverset(o+)(H)(4) salt give brown ppt with K(2)HgI(4); brown...

    Text Solution

    |

  14. Even in the absence of group II,colloidal yellowish ppt appears on pa...

    Text Solution

    |

  15. Hypo gives (a) ppt. with AgNO(3) which changes to (b) .

    Text Solution

    |

  16. Reddish brown colouration when neutral FeCl(3) is added to the CH(3)C...

    Text Solution

    |

  17. As(2)S(3) is soluble in(NH(4))(2)S(2) (yellow ammonium sulphide) due ...

    Text Solution

    |

  18. On heating the salt with NHO(3) and ammonium molybdate , formation o...

    Text Solution

    |

  19. Cu^(2+) gives white ppt. of (a) with (b) and deep blue colour of (c )...

    Text Solution

    |

  20. AgCl is soluble in (a) and Ag^(o+) is present in (b).

    Text Solution

    |