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NO(3)^(Θ) is detected by (a) when (b)is...

`NO_(3)^(Θ)` is detected by (a) _____when (b)_____is formed on the addition of `FeSO_(4)` and cone `H_(2)SO_(4)`

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To solve the question regarding the detection of nitrate ions (NO₃⁻) using ferrous sulfate (FeSO₄) and concentrated sulfuric acid (H₂SO₄), we can break it down into the following steps: ### Step-by-Step Solution: 1. **Understanding the Detection of Nitrate Ions**: - Nitrate ions (NO₃⁻) can be detected using a specific test known as the "ring test". This test is commonly used for identifying the presence of nitrate ions in a sample. 2. **Performing the Ring Test**: - In the ring test, a small amount of ferrous sulfate (FeSO₄) is added to the solution containing the nitrate ions. 3. **Adding Concentrated Sulfuric Acid**: - After adding the ferrous sulfate, concentrated sulfuric acid (H₂SO₄) is carefully added to the mixture. It is important to add the acid slowly and carefully to avoid any violent reactions. 4. **Observation of the Reaction**: - Upon the addition of concentrated sulfuric acid, a brown ring is formed at the interface of the two liquids. This brown ring is indicative of the presence of nitrous acid (HNO₂) which is formed in situ from the reaction of nitrate ions with ferrous ions. 5. **Formation of the Compound**: - The compound that is formed during this reaction is known as "ferrous nitrate" or "iron(II) nitrate", which can be represented as Fe(H₂O)₃NO₂⁻. This compound is responsible for the characteristic brown ring observed in the test. ### Final Answer: (a) **Ring test** (b) **Fe(H₂O)₃NO₂⁻**
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Fill In The Blanks)
  1. Iron (II)sulphide gives foul smell of (a).

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  2. AgBr is soluble in hypo forming (a) .

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  3. NO(3)^(Θ) is detected by (a) when (b)is formed on the addition of FeS...

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  4. CI^(Θ)is confirmed by (a) .

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  5. Addition of one drop of HNO(3) in group (III) analysis is to (a) .

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  6. Reagent that can detect any of Fe^(3+),Co^(2+) and Cu^(2+) is (a) .

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  7. While testing borate, green edged flame is due so formation of (a) .

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  8. When SO(2) is passed into suspention of CaSO(3) in water (a) is form...

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  9. Alkaline Noverset(o+)(H)(4) salt give brown ppt with K(2)HgI(4); brown...

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  10. Even in the absence of group II,colloidal yellowish ppt appears on pa...

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  11. Hypo gives (a) ppt. with AgNO(3) which changes to (b) .

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  12. Reddish brown colouration when neutral FeCl(3) is added to the CH(3)C...

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  13. As(2)S(3) is soluble in(NH(4))(2)S(2) (yellow ammonium sulphide) due ...

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  14. On heating the salt with NHO(3) and ammonium molybdate , formation o...

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  15. Cu^(2+) gives white ppt. of (a) with (b) and deep blue colour of (c )...

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  16. AgCl is soluble in (a) and Ag^(o+) is present in (b).

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  17. Hg(2)Cl(2) aprecipitate if (a) is greater than K(sp) (Hg(2)Cl(2)).

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  18. Sodium carbonate and mixture are taken in ratio while perparing sodi...

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  19. BaBr(2) in aq solution give yellow ppt ,with (a) as well as with (b).

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  20. Yellow ppt of (a) is formed when CoCl(2) reacts with excess of KNO(...

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