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Reddish brown colouration when neutral ...

Reddish brown colouration when neutral `FeCl_(3)` is added to the `CH_(3)CO O^(Θ)` aq solution is due to the formation of (a) ____.

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To solve the question regarding the reddish brown coloration when neutral ferric chloride (FeCl₃) is added to an aqueous solution of acetate ions (CH₃COO⁻), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this case are neutral ferric chloride (FeCl₃) and acetate ions (CH₃COO⁻) in an aqueous solution. 2. **Understand the Reaction**: - When FeCl₃ is added to an acetate ion solution, the ferric ions (Fe³⁺) from FeCl₃ interact with the acetate ions (CH₃COO⁻). 3. **Formation of Complex**: - The ferric ions can form a complex with acetate ions. The reaction can be represented as: \[ \text{Fe}^{3+} + 6 \text{CH}_3\text{COO}^- \rightarrow \text{Fe(CH}_3\text{COO)}_6^{3-} \] - This complex is known as ferric acetate. 4. **Color Observation**: - The complex formed, specifically \(\text{Fe(OH)}_2(\text{CH}_3\text{COO})_6^{+}\), gives a reddish-brown coloration. This is characteristic of ferric compounds. 5. **Conclusion**: - Therefore, the reddish brown coloration when neutral FeCl₃ is added to CH₃COO⁻ aqueous solution is due to the formation of the complex \(\text{Fe(OH)}_2(\text{CH}_3\text{COO})_6^{+}\). ### Final Answer: The reddish brown coloration when neutral FeCl₃ is added to CH₃COO⁻ aqueous solution is due to the formation of \(\text{Fe(OH)}_2(\text{CH}_3\text{COO})_6^{+}\). ---
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Fill In The Blanks)
  1. NO(3)^(Θ) is detected by (a) when (b)is formed on the addition of FeS...

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  2. CI^(Θ)is confirmed by (a) .

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  3. Addition of one drop of HNO(3) in group (III) analysis is to (a) .

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  4. Reagent that can detect any of Fe^(3+),Co^(2+) and Cu^(2+) is (a) .

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  5. While testing borate, green edged flame is due so formation of (a) .

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  6. When SO(2) is passed into suspention of CaSO(3) in water (a) is form...

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  7. Alkaline Noverset(o+)(H)(4) salt give brown ppt with K(2)HgI(4); brown...

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  8. Even in the absence of group II,colloidal yellowish ppt appears on pa...

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  9. Hypo gives (a) ppt. with AgNO(3) which changes to (b) .

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  10. Reddish brown colouration when neutral FeCl(3) is added to the CH(3)C...

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  11. As(2)S(3) is soluble in(NH(4))(2)S(2) (yellow ammonium sulphide) due ...

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  12. On heating the salt with NHO(3) and ammonium molybdate , formation o...

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  13. Cu^(2+) gives white ppt. of (a) with (b) and deep blue colour of (c )...

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  14. AgCl is soluble in (a) and Ag^(o+) is present in (b).

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  15. Hg(2)Cl(2) aprecipitate if (a) is greater than K(sp) (Hg(2)Cl(2)).

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  16. Sodium carbonate and mixture are taken in ratio while perparing sodi...

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  17. BaBr(2) in aq solution give yellow ppt ,with (a) as well as with (b).

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  18. Yellow ppt of (a) is formed when CoCl(2) reacts with excess of KNO(...

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  19. Microcosmic salt reacts with coloured ions to form characteristic bead...

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  20. Th esodium carbobate bead test test is which Na(2)CO(3) is along in...

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