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Microcosmic salt reacts with coloured io...

Microcosmic salt reacts with coloured ions to form characteristic bead which is due to formation

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To solve the question regarding the reaction of microcosmic salt with colored ions to form characteristic beads, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Microcosmic Salt**: - Microcosmic salt is chemically known as sodium ammonium hydrogen phosphate (NaNH4HPO4). It is commonly used in qualitative inorganic analysis. 2. **Reaction with Colored Ions**: - When microcosmic salt is heated with colored metal ions (like copper ions), it forms a characteristic bead. This is due to the formation of a metal phosphate. 3. **Formation of Sodium Metaphosphate**: - Upon heating, microcosmic salt decomposes to form sodium metaphosphate (NaPO3). The reaction can be represented as: \[ \text{NaNH}_4\text{HPO}_4 \rightarrow \text{NaPO}_3 + \text{NH}_3 + \text{H}_2\text{O} \] 4. **Reaction with Copper Oxide**: - The sodium metaphosphate then reacts with copper oxide (CuO) to form sodium copper phosphate (NaCuPO4), which is a blue compound. The reaction can be represented as: \[ \text{NaPO}_3 + \text{CuO} \rightarrow \text{NaCuPO}_4 \] 5. **Characteristic Bead Formation**: - The resulting sodium copper phosphate (NaCuPO4) forms a blue bead when heated in the flame. This blue color is characteristic of copper ions and indicates the presence of copper in the sample. 6. **Conclusion**: - The characteristic bead formed when microcosmic salt reacts with colored ions is primarily due to the formation of metal phosphates, specifically sodium copper phosphate in the case of copper ions.
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Borax [Na_(2)B_(4)O_(7).10H_(2)O] when heated on platinum loop it gives a dark transparent glass like bead. The hot bead is dipped in the salt till it reacts with transition metal oxide. It produces characteristic bead of meta borate. {:(" Colour of the bead"," lon"),("(a) Blue green or light blue",Cu^(+2)),("(b) Yellow",Fe^(+2)or Fe^(+3)),("(c) Green",Cr^(+3)),("(d) Violet",Mn^(+2)),("(e) Dark blue",Co^(+2)),("(f) Brown",Ni^(+2)):} Glassy bead is of

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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Fill In The Blanks)
  1. NO(3)^(Θ) is detected by (a) when (b)is formed on the addition of FeS...

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  2. CI^(Θ)is confirmed by (a) .

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  3. Addition of one drop of HNO(3) in group (III) analysis is to (a) .

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  4. Reagent that can detect any of Fe^(3+),Co^(2+) and Cu^(2+) is (a) .

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  5. While testing borate, green edged flame is due so formation of (a) .

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  6. When SO(2) is passed into suspention of CaSO(3) in water (a) is form...

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  7. Alkaline Noverset(o+)(H)(4) salt give brown ppt with K(2)HgI(4); brown...

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  8. Even in the absence of group II,colloidal yellowish ppt appears on pa...

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  9. Hypo gives (a) ppt. with AgNO(3) which changes to (b) .

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  10. Reddish brown colouration when neutral FeCl(3) is added to the CH(3)C...

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  11. As(2)S(3) is soluble in(NH(4))(2)S(2) (yellow ammonium sulphide) due ...

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  12. On heating the salt with NHO(3) and ammonium molybdate , formation o...

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  13. Cu^(2+) gives white ppt. of (a) with (b) and deep blue colour of (c )...

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  14. AgCl is soluble in (a) and Ag^(o+) is present in (b).

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  15. Hg(2)Cl(2) aprecipitate if (a) is greater than K(sp) (Hg(2)Cl(2)).

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  16. Sodium carbonate and mixture are taken in ratio while perparing sodi...

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  17. BaBr(2) in aq solution give yellow ppt ,with (a) as well as with (b).

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  18. Yellow ppt of (a) is formed when CoCl(2) reacts with excess of KNO(...

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  19. Microcosmic salt reacts with coloured ions to form characteristic bead...

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  20. Th esodium carbobate bead test test is which Na(2)CO(3) is along in...

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