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A solutionf of a metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless solution.Moreover, the solution of metal ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a deep-blue crystalline precipitate. The metal ions is

A

`Pb^(2+)`

B

`Hg^(2+)`

C

`Cu^(2+)`

D

`Co^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
b,c

`Hg^(2+) + 2I^(Theta) rarr HgI_(2) darr `(Scarlet red precipitate )
`HgI_(2) + 2I^(theta) rarr [HgI_(4)]^(2+)`
`Hg^(2+) + Co(SCN)_(2) rarr underset("Deep blue crystalaline")(Hg(SCN)_(2)) + Co^(2+)`
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