Home
Class 11
CHEMISTRY
Arrange in decreasing order of basicity....

Arrange in decreasing order of basicity.
(1) `m-BO_2-C_6H_4-NH_2`
(2) `C_6H_5NH_2`
(3) `p-NO_2-C_6H_4NH_2`
(4) `o-NO_2-C_6H_4NH_2`

Text Solution

AI Generated Solution

To arrange the given compounds in decreasing order of basicity, we need to analyze the effects of substituents on the nitrogen atom in each compound. The basicity of an amine is influenced by the availability of the lone pair of electrons on the nitrogen atom. If the lone pair is more available, the compound will be more basic. ### Step-by-Step Solution: 1. **Identify the Compounds**: - (1) `m-BO_2-C_6H_4-NH_2` (meta-nitroaniline) - (2) `C_6H_5NH_2` (aniline) - (3) `p-NO_2-C_6H_4-NH_2` (para-nitroaniline) ...
Promotional Banner

Topper's Solved these Questions

  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective|11 Videos

  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Concept|17 Videos

  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Analytical and Descriptive|1 Videos

  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Analytical and Descriptive Type|3 Videos

  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos

Similar Questions

Explore conceptually related problems

Arrange the following anilines in decreasing order of basicity 1. C_(6)H_(5)NH_(2) 2. o-CH_(3)C_(6)H_(4)NH_(2) 3. m-CH_(3)C_(6)H_(4)NH_(2) 4. p-CH_(3)C_(6)H_(4)NH_(2)

Arrange the following compounds in increasing order of basicity: CH_3NH_2 , (CH_3)_2NH , NH_3 , C_6H_5NH_2

The decreasing order of the basic character of NH_(3), CH_(3)NH_(2), C_(2)H_(5)NH_(2) and C_(6)H_(5)NH_(2) is

Arrange the following in increasing order of their basic strength : (i) C_(2)H_(5)NH_(2), C_(6)H_(5)NH_(2), C_(6)H_(5)CH_(2)NH_(2) and (C_(2)H_(5))_(2)NH (ii) C_(2)H_(5)NH_(2), (C_(2)H_(5))_(2)NH, (C_(2)H_(5))_(3)N, C_(6)H_(5)NH_(2) (iii) CH_(3)NH_(2), (CH_(3))_(2)NH, (CH_(3))_(3)N, C_(6)H_(5)NH_(2),C_(6)H_(5)CH_(2)NH_(2)

Arrange the following in increasing order of their basic strength : CH_3 NH_2 , (CH_3)_2 NH , (CH_3)_3 N, C_6 H_5 NH_2 ,C_6 H_5 CH_2 NH_2

Arrange the following in increasing order of their basic strength : C_2 H_5 NH_2 . C_6 H_5 NH_2 ,CH_2 and (C_2 H_5) NH

Arrange the following in incresing order of basic strength : C_(6)H_(5)NH_(2),C_(2)H_(5)NHCH_(3),C_(6)H_(5)N(CH_(3))_(2) .

Arrange the following In decreasing order of p K_b values (I) C_2H_5 NH_2 (II) PhNHMe (III) (C_2H_5)_2 NH (IV) PhNH_2

Arrange the following in decreasing order of their basic strength : C_(6)H_(5)NH_(2),C_(2)H_(5)NH_(2),(C_(2)H_(5))_(2)NH_(3)

Rerrange the following in an increasing order of their basic strengths: C_(6)H_(5)NH_(2),C_(6)H_(5)N(CH_(3))_(2),(C_(6)H_(5))_(2) NH and CH_(3)NH_(2) .

CENGAGE CHEMISTRY ENGLISH-GENERAL ORGANIC CHEMISTRY-Solved Example
  1. Which of the following is the most stable resonance structure .

    Text Solution

    |

  2. Which of the following is a most likely product from the reaction as s...

    Text Solution

    |

  3. Give the stability of the following resonance structures (a) H(2)C =...

    Text Solution

    |

  4. Write the correct resonance structure of the given compound. .

    Text Solution

    |

  5. The correct stability order for the following species is

    Text Solution

    |

  6. Explain the following : (a) Why MeNH overset (oplus) CH2 (I) is more...

    Text Solution

    |

  7. Give decreasing order of the stabilities of the following :

    Text Solution

    |

  8. Arrange the following compounds in the order of increasing boiling poi...

    Text Solution

    |

  9. (I) Arrange the compounds (a0 in the order of decreasing boilling poin...

    Text Solution

    |

  10. Arrange the following in the decreasing order of boiling points : (i...

    Text Solution

    |

  11. Arrange the following alcohols : In the decreasing order of their bo...

    Text Solution

    |

  12. Arrange the following alcohols in the decreasing order of reactivity t...

    Text Solution

    |

  13. Arrange the following alchols in the decreasing order of their reactiv...

    Text Solution

    |

  14. Arrange the following in the decreasing order of acidity : (1) n-But...

    Text Solution

    |

  15. Arrange the following in the order of decreasing basic character : (1...

    Text Solution

    |

  16. Arrange in decreasing order of basicity. (1) m-BO2-C6H4-NH2 (2) C6...

    Text Solution

    |

  17. Compare the acidities of amide (R-underset(O)underset (||)(C)-NH(2)) a...

    Text Solution

    |

  18. Which of the following pairs would have higher boiling points ?

    Text Solution

    |