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Compare the acidities of amide (R-unders...

Compare the acidities of amide `(R-underset(O)underset (||)(C)-NH_(2))` and sulphonamide `(R-underset(O)underset(||)overset(O)overset(|)S-NH_(2))`

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To compare the acidities of amide (RCONH₂) and sulfonamide (RSO₂NH₂), we need to analyze the stability of their conjugate bases. The more stable the conjugate base, the stronger the acid. ### Step 1: Identify the conjugate bases - For amide (RCONH₂), the conjugate base is formed by deprotonating the NH₂ group: \[ \text{Conjugate base of amide: } RCO^-NH_2 \] - For sulfonamide (RSO₂NH₂), the conjugate base is formed similarly: ...
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With the help of F.C . Explain which Lewis structure is more stable for the following molecules : (a) N_(2)O: (i) :^(Theta)ddotN =overset(2+)O=ddotN:^(Theta) or (ii) :N -=overset(o+)N-ddotunderset(..)O:^(Theta) (b). H_(2)SO_(4): (i) H-O-overset( :ddotO:^(Theta))overset(|)underset(Theta)underset( :underset(..)O: )underset(|)(S^(+2))-O-H or (ii) H-O-underset( underset(..):O)underset(||)overset(ddotO: )overset(||)S-O-H HNO_(3)(i) H-O-underset(Theta)underset( :underset(..)O: )underset(|)overset(o+)N=ddotO: or (ii) H-O-underset(underset(..):O:_(Theta))underset(|)overset(+2)N-underset(..)ddotO:^(Theta) (d). CI_(2)O: (i) underset(..):ddotCI-ddotunderset(..)O-underset(..)ddotCI: or (ii) :underset(..)ddotO-underset(..)ddot(CI)-underset(..)ddotCI:

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CENGAGE CHEMISTRY ENGLISH-GENERAL ORGANIC CHEMISTRY-Solved Example
  1. Which of the following is the most stable resonance structure .

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  2. Which of the following is a most likely product from the reaction as s...

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  3. Give the stability of the following resonance structures (a) H(2)C =...

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  4. Write the correct resonance structure of the given compound. .

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  5. The correct stability order for the following species is

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  6. Explain the following : (a) Why MeNH overset (oplus) CH2 (I) is more...

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  7. Give decreasing order of the stabilities of the following :

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  8. Arrange the following compounds in the order of increasing boiling poi...

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  9. (I) Arrange the compounds (a0 in the order of decreasing boilling poin...

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  10. Arrange the following in the decreasing order of boiling points : (i...

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  11. Arrange the following alcohols : In the decreasing order of their bo...

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  12. Arrange the following alcohols in the decreasing order of reactivity t...

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  13. Arrange the following alchols in the decreasing order of their reactiv...

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  14. Arrange the following in the decreasing order of acidity : (1) n-But...

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  15. Arrange the following in the order of decreasing basic character : (1...

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  16. Arrange in decreasing order of basicity. (1) m-BO2-C6H4-NH2 (2) C6...

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  17. Compare the acidities of amide (R-underset(O)underset (||)(C)-NH(2)) a...

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  18. Which of the following pairs would have higher boiling points ?

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