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In which of the following reactions, rea...

In which of the following reactions, rearrangement is possible ?

A

`E1`

B

`SN^1`

C

`SN^(2')`

D

`E1cB`

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The correct Answer is:
To determine in which of the following reactions rearrangement is possible, we will analyze each reaction type: E1, SN1, SN2, and E1CB. ### Step-by-Step Solution: 1. **Understanding E1 Reactions**: - E1 stands for unimolecular elimination. This reaction proceeds through a two-step mechanism where a carbocation intermediate is formed after the leaving group departs. - Since rearrangement can occur at the carbocation stage (to form a more stable carbocation), rearrangement is possible in E1 reactions. 2. **Understanding SN1 Reactions**: - SN1 stands for unimolecular nucleophilic substitution. Similar to E1, this reaction also involves a two-step mechanism where a carbocation intermediate is formed. - Rearrangement can occur at the carbocation stage to form a more stable carbocation, making rearrangement possible in SN1 reactions. 3. **Understanding SN2 Reactions**: - SN2 stands for bimolecular nucleophilic substitution. This reaction occurs in a single step, where the nucleophile attacks the substrate as the leaving group departs. - Since there is no carbocation intermediate formed in SN2 reactions, rearrangement does not occur in this type of reaction. 4. **Understanding E1CB Reactions**: - E1CB stands for unimolecular elimination via a conjugate base. This reaction occurs under basic conditions and involves the formation of a carbanion intermediate. - The carbanion formed is typically stable and does not undergo rearrangement because it is an irreversible step. Thus, rearrangement is not possible in E1CB reactions. ### Conclusion: From the analysis above, rearrangement is possible in E1 and SN1 reactions due to the presence of carbocation intermediates. Rearrangement is not possible in SN2 and E1CB reactions. **Correct Options**: E1 and SN1 (Options A and B)

To determine in which of the following reactions rearrangement is possible, we will analyze each reaction type: E1, SN1, SN2, and E1CB. ### Step-by-Step Solution: 1. **Understanding E1 Reactions**: - E1 stands for unimolecular elimination. This reaction proceeds through a two-step mechanism where a carbocation intermediate is formed after the leaving group departs. - Since rearrangement can occur at the carbocation stage (to form a more stable carbocation), rearrangement is possible in E1 reactions. ...
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CENGAGE CHEMISTRY ENGLISH-ORGANIC REACTION MECHANISM-Multiple Correct
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  2. Which of the following transformations are feasible ?

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  4. Which of the following statements are correct ?

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  5. Which of the following is//are the rate determining step (s) of the gi...

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  6. The products in the given reaction are : .

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  7. Which of the following statements are correct about the addition of HB...

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  8. Which of the following statements are correct ?

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  9. In which of the following reactions, rearrangement is possible ?

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  10. Which of the following is an example of nucleophilic addition to aceta...

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  11. In which of the reactions, there is a migration of alkyl group to carb...

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  12. Which of the following statements are correct ?

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  13. Which of the following statements/reactions are correct ?

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  14. Which of the following statements is//are correct ?

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  15. Consider the following reactions : (I) Me - underset ((A)) -= - Me o...

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  16. Consider the following reactions : Which of the following stateme...

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  17. Consider the following reactions : Which of the following stateme...

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  18. Which of the following statements/reactions are correct ?

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  19. Consider the following compounds Which of the following statements are...

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  20. Which of the following reactions are both stereospecific and regiosele...

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