Home
Class 11
CHEMISTRY
Which of the following statements is//ar...

Which of the following statements is//are correct ?

A

Protic solvents solvate the nucleophile, lower enthalpy of nucleophiles, increase `Delta G`, and decrease the reaction rate of `SN^2` reaction.

B

`SN^1` reactions are favoured in protic solvents.

C

Crown ether increases the reactivity of nucleophile by solvating its cation.

D

`SN^2` reactions are more favoured in protic solvents.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements are correct regarding SN1 and SN2 reactions in the context of protic solvents and crown ethers, let's analyze each statement step by step. ### Step-by-Step Solution: 1. **Understanding Protic Solvents**: - Protic solvents are those that have hydrogen atoms attached to electronegative atoms like oxygen or nitrogen. They can donate protons (H⁺) to solutes. - This property allows protic solvents to solvate nucleophiles effectively. **Hint**: Recall that protic solvents can stabilize nucleophiles by solvation, which can affect reaction rates. 2. **Evaluating Statement A**: - Statement A claims that protic solvents solvate nucleophiles, which lowers the enthalpy of nucleophiles, increases ΔG, and decreases the reaction rate of SN2 reactions. - This statement is correct because the solvation of nucleophiles by protic solvents can indeed lower their reactivity, leading to a higher activation energy (ΔG) and thus a slower reaction rate for SN2 reactions. **Hint**: Consider how solvation affects nucleophile reactivity in SN2 mechanisms. 3. **Evaluating Statement B**: - Statement B states that SN1 reactions are favored in protic solvents. - This is also correct because protic solvents stabilize the carbocation intermediate formed during the ionization of the substrate, which is essential for SN1 reactions. **Hint**: Think about the role of solvent in stabilizing charged intermediates in SN1 reactions. 4. **Evaluating Statement C**: - Statement C asserts that crown ethers increase the reactivity of nucleophiles while solvating their cations. - This statement is true as crown ethers can complex with cations (like K⁺) and effectively solvate them, which enhances the nucleophilicity of the anion. **Hint**: Remember that crown ethers can selectively bind cations, affecting the overall reactivity of nucleophiles. 5. **Evaluating Statement D**: - Statement D claims that SN2 reactions are more favored in protic solvents. - This statement is incorrect. SN2 reactions are generally favored in aprotic solvents because protic solvents can hinder the nucleophile's approach to the electrophile due to solvation. **Hint**: Recall the differences in solvent effects on SN1 and SN2 mechanisms. ### Conclusion: The correct statements are A, B, and C. Statement D is incorrect. ### Final Answer: - **Correct Statements**: A, B, C - **Incorrect Statement**: D

To determine which statements are correct regarding SN1 and SN2 reactions in the context of protic solvents and crown ethers, let's analyze each statement step by step. ### Step-by-Step Solution: 1. **Understanding Protic Solvents**: - Protic solvents are those that have hydrogen atoms attached to electronegative atoms like oxygen or nitrogen. They can donate protons (H⁺) to solutes. - This property allows protic solvents to solvate nucleophiles effectively. ...
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Single correct|43 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning|12 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Comprehension|35 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY ENGLISH|Exercise Chemical Equilibrium|73 Videos
  • P-BLOCK GROUP 13 - BORON FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise Archives (Subjecive)|9 Videos

Similar Questions

Explore conceptually related problems

Which of the following statement is/are correct?

Which of the following statement is/are correct?

Which of the following statement is/are correct ?

Which of the following statement is/are correct?

Which of the following statement is/are correct ?

Which of the following statement is/are correct

Which of the following statement is/are correct?

Which of the following statement is/are correct?

Which of the following statement is/are correct?

Which of the following statement is/are correct :

CENGAGE CHEMISTRY ENGLISH-ORGANIC REACTION MECHANISM-Multiple Correct
  1. Which of the following reactions are feasible ?

    Text Solution

    |

  2. Which of the following transformations are feasible ?

    Text Solution

    |

  3. In which of the following reactions, the intermediate species acyl nit...

    Text Solution

    |

  4. Which of the following statements are correct ?

    Text Solution

    |

  5. Which of the following is//are the rate determining step (s) of the gi...

    Text Solution

    |

  6. The products in the given reaction are : .

    Text Solution

    |

  7. Which of the following statements are correct about the addition of HB...

    Text Solution

    |

  8. Which of the following statements are correct ?

    Text Solution

    |

  9. In which of the following reactions, rearrangement is possible ?

    Text Solution

    |

  10. Which of the following is an example of nucleophilic addition to aceta...

    Text Solution

    |

  11. In which of the reactions, there is a migration of alkyl group to carb...

    Text Solution

    |

  12. Which of the following statements are correct ?

    Text Solution

    |

  13. Which of the following statements/reactions are correct ?

    Text Solution

    |

  14. Which of the following statements is//are correct ?

    Text Solution

    |

  15. Consider the following reactions : (I) Me - underset ((A)) -= - Me o...

    Text Solution

    |

  16. Consider the following reactions : Which of the following stateme...

    Text Solution

    |

  17. Consider the following reactions : Which of the following stateme...

    Text Solution

    |

  18. Which of the following statements/reactions are correct ?

    Text Solution

    |

  19. Consider the following compounds Which of the following statements are...

    Text Solution

    |

  20. Which of the following reactions are both stereospecific and regiosele...

    Text Solution

    |