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Complete the following: a....

Complete the following:
a.

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a.
b.
c.
d. It involves 1,4-addition followed by tautomerisation.

e.
f.
g.
h. `A implies PhCOCI`
i.
j. Perkin reaction:

k.
l. Reimer-Tiemann reaction:
m.
n.
o.
p.
`(B) rArr underset(("Pinacol) (Benzopinacol"))(Ph-underset(OH)underset(|)overset(Ph)overset(|)(C)-underset(OH)underset(|)overset(Ph)overset(|)(C)-Ph)`
q. Cross Cannizzaro reaction:

(B) `implies HCOOK`
r. Fridel-Crafts reaction: Acetylation `(ZnCI_(2)+HCI)` (Lewis acid).

s. `SeO_(2)` oxidises active methylene group to carbonyl group.
`[(A) implies PhCOCHO)]`
t. `CH_(3)COOH+KCN rarr HCN+CN_(3)COOK`. The nucleophilic 1,4-addition takes place.

u.
v. Fries migration of isopropyl group:

w.
x. (A) `implies PhCOOK, (B) implies`
y.
z. Intermolecular Cannizzaro reaction:

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CENGAGE CHEMISTRY ENGLISH-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Subjective
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  3. Complete the following: a.

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  4. a. PhCOH(3) overset(NaOCI)underset(NaOH)rarr PhCOONa+CHCl(3) b. B...

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  5. Convert salicyaldeyde into (coumarin).

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  6. a.

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  7. (B)overset(Θ)(OH)larr CH(2)=CH-CHO overset(AI(OEt)(3))rarr (A)

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  8. p-Hydroxybenzaldehyde does not undergo Cannizzaro reaction. Explain.

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  9. Complete the following reaction

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  10. Convert HCHO to glycol in one step only.

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  11. Convert and vice versa.

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  12. Convert benzence to PhCHO in one step only.

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  13. An aromatic kentone (X) has the molecular formula C(10)H(12)O(2). On v...

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  14. A natural compound (A) (C(7)H(6)O) forms an oxime. When (A) is treated...

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  15. An organic compound (A) (C(8)H(14)O) forms an oxime and gives a positi...

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  16. Compound (A) (C(6)H(12)O(2)) on reduction with LiAlH(4) yielded two co...

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  17. Hydrocarbon (X), C(7)H(12), on reaction with boron hydride followed by...

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  18. An organic compound (A) (C(6)H(10)) on reaction with CH(3)MgBr followe...

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  19. An organic compound (A) contaning C, H, and O (16.32%) does not decolo...

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  20. A 0.535 gm mixture of ethanol and acetaldehyde when heated with Fehlin...

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