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A natural compound (A) (C(7)H(6)O) forms...

A natural compound (A) `(C_(7)H_(6)O)` forms an oxime. When (A) is treated with acetic anhydride and sodium acetate, it yields a product (B) which decolourises alkaline `KMnO_(4)` solution and also gives effervscence with `NaHCO_(3)`. Explain the reaction and assign structures to (A) and (B).

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To solve the problem step by step, we will identify the natural compound (A) with the formula \( C_7H_6O \), determine its structure, and then analyze the reaction with acetic anhydride and sodium acetate to find the product (B). ### Step 1: Determine the structure of compound (A) 1. **Calculate the degree of unsaturation**: The formula for degree of unsaturation (DU) is: \[ DU = \frac{2C + 2 - H}{2} ...
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An organic compound (A) (C_(8)H_(14)O) forms an oxime and gives a positive haloform reaction. On ozonolysis, it gives acetone and a compound (B) (C_(5)H_(8)O_(2)) . (B) forms a dioxime and on subjecting to oxidation reaction gives an acid (C ) (C_(4)H_(6)O_(4)) . On treatment with excess of ammonia and strong heating, (C ) gives a neutral compound (D) (C_(4)H_(5)O_(2)N) . (D) on distillation with zinc dust forms pyrrloe. Suggest the possible structures of (A), (B), (C ), and (D). Explain the chemical reactions involved.

Compound (A) (C_(4)H_(8)O_(3)) reacts with NaHCO_(3) and evolves CO_(2)(g). (A) reacts with LAH to give a compound (B) which is a chiral. The structure of (A) is:

Compound (A) C_(5)H_(8)O_(2) liberated CO_(2) on reaction with sodium bicarbonate. It exists in two forms neither of which is optically active. It yielded compound (B) C_(5)H_(10)O_(2) on hydrogenation. Compound (B) can be separated into enantiomorphs. Write structures of (A) and (B).

Compound (A) C_(6)H_(12) gives a positive test with bromine in carbon tetrachloride. Reaction of (A) with alkaline KMnO_(4) yields only (B) which is the potassium salt of an acid. Write structure formulae and IUPAC name of (A) and (B).

Compound (X) with molecular formula C_(3)H_(8)O is treated with acidified potassium dichromate to form a product (Y) with molecular formula C_(3)H_(6)O . (Y) does not form a shining silver mirror on warming with ammoniacal AgNO_(3) . (Y) when treated with an aqueous solution of NH_(2)CONHNH_(2).HCl and sodium acetate, gives a product (Z). The structure of (Z) is

An organic compound A has the molecular formula of C_7H_6O . When A is treated with NaOH followed by acid hydrolysis, it gives two products, B and C. When B is oxidised, it gives A. When A and C are each treated separately with PCl_5 , they give two different organic products D and E. Give the chemical reaction when A is treated with NaOH and name the reaction.

A compound (A) is a sodium salt of dibasic acid and on electrolysis gives a gas (B), gas CO_(2) at anode, and H_(2)(g) at cathode. Gas (B) does not give any test for unsaturation, i.e., it does not decolourise Br_(2) water solution and aqueous KMnO_(4) solution. Gas (B) on reaction with (H_(2)+Pt) at room temperature does not react but at 120^(@)C , gas (B) gives butane. Identfy (A) and (B)

An alkene A on ozonolysis yields acetone and an aldehyde. The aldehyde is easily oxidised to an acid B. When B is treated with bromine in presence of yields a compound C which on hydrolysis gives a hydroxyle acid D. This acid can also be obatined from acetone by the reaction with hydrogen cyanide followed by hydrolysis. Identify the compounds A, B C and D.

CENGAGE CHEMISTRY ENGLISH-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Subjective
  1. p-Hydroxybenzaldehyde does not undergo Cannizzaro reaction. Explain.

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  2. Complete the following reaction

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  3. Convert HCHO to glycol in one step only.

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  4. Convert and vice versa.

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  5. Convert benzence to PhCHO in one step only.

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  6. An aromatic kentone (X) has the molecular formula C(10)H(12)O(2). On v...

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  7. A natural compound (A) (C(7)H(6)O) forms an oxime. When (A) is treated...

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  8. An organic compound (A) (C(8)H(14)O) forms an oxime and gives a positi...

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  9. Compound (A) (C(6)H(12)O(2)) on reduction with LiAlH(4) yielded two co...

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  10. Hydrocarbon (X), C(7)H(12), on reaction with boron hydride followed by...

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  11. An organic compound (A) (C(6)H(10)) on reaction with CH(3)MgBr followe...

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  12. An organic compound (A) contaning C, H, and O (16.32%) does not decolo...

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  13. A 0.535 gm mixture of ethanol and acetaldehyde when heated with Fehlin...

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  14. An organic compound (A) contains 79.25% C, 5.66% H, and 15.09% O. It h...

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  15. An organic compound (A) containing 60.12% (C ) and 13.3% H has vapour ...

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  16. Two organic compounds (A) and (B) containing 62.01% C and 10.3% H reac...

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  17. An organic compound (A) (C(5)H(7)OCl) reacts rapidly with ethanol to g...

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  18. An organic compound (A) contains 87.27% C and 13.73% H. Its vapour den...

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  19. An organic compound (A) C(4)H(9)Cl on reacting with aqueous KOH gives ...

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  20. An alkyne with five carbon atoms per molecule when passed through dilu...

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