Home
Class 12
CHEMISTRY
An organic compound (A) (C(5)H(7)OCl) re...

An organic compound (A) `(C_(5)H_(7)OCl)` reacts rapidly with ethanol to give (B) `(C_(7)H_(12)O_(2))`. (A) also reacts with water to produce an acid which reacts with bromine to give (C ) `(C_(5)H_(8)Br_(2)O_(2))`. (B) on boiling with `H_(2)SO_(4)` forms an acid (D). When (D) is oxidised with `KMnO_(4)` an acid (E ) `(C_(4)H_(6)O_(3))` is produced. On mild heating, (E ) gives (F) `(C_(3)H_(6)O)` which cannot be oxidised by ammoniacal `AgNO_(3)`. Identify the compounds (A) to (F).

Text Solution

AI Generated Solution

To solve the problem step by step, we will identify the compounds (A) to (F) based on the information provided in the question. ### Step 1: Identify Compound A Given that compound (A) has the formula \(C_5H_7OCl\) and reacts with ethanol to form compound (B) \(C_7H_{12}O_2\), we can deduce that compound (A) is likely an allylic chloride. The presence of the carbonyl chloride (COCl) suggests that it is a chloroalkene. **Assumption**: Compound (A) is likely 3-chlorobut-2-ene: \[ \text{A: } CH_2=CH-CHCl-CH_3 ...
Promotional Banner

Topper's Solved these Questions

  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Concept Application|20 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Linked Comprehension|59 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples|13 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Analytical And Descriptive|15 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos

Similar Questions

Explore conceptually related problems

Compound (A) (C_(4)H_(8)O_(3)) reacts with NaHCO_(3) and evolves CO_(2)(g). (A) reacts with LAH to give a compound (B) which is a chiral. The structure of (A) is:

An organic compound A, C_(5)H_(8)O reacts with H_(2)O, NH_(3) and CH_(3)COOH as described below A is

Compound (X ) C_(7)H_(8)O dissolves in NaOH but not in NaHCO_(3) ( X) reacts rapidly with Br_(2) to give (Y) C_(7) H_(5) O Br_(3) Product structure of X would be

A compound (A) C_(5)H_(10) Cl_(2) on hydrolysis gives C_(5)H_(10)O which reacts with NH_(2)OH , forms iodoform but does not give Fehling test (A) is :

An organic compound (A) of molecular formula C_(5)H_(8) when treated with Na in liquid ammonia followed by reaction with -Propyl iodide yeidls (B) C_(8)H_(12) (A) gives a ketone C_(5)H_(10)O (e) when treated with dil H_(2)SO_(4) and HgSO_(4) (B) on oxidation with alkaline KMnO_(4) gives two isomeric acids (D) and (E) C_(4)H_(8)O_(2) . Give structures of compounds (A) to (E) with proper reasoning .

An organic compound (A) (C_(8)H_(14)O) forms an oxime and gives a positive haloform reaction. On ozonolysis, it gives acetone and a compound (B) (C_(5)H_(8)O_(2)) . (B) forms a dioxime and on subjecting to oxidation reaction gives an acid (C ) (C_(4)H_(6)O_(4)) . On treatment with excess of ammonia and strong heating, (C ) gives a neutral compound (D) (C_(4)H_(5)O_(2)N) . (D) on distillation with zinc dust forms pyrrloe. Suggest the possible structures of (A), (B), (C ), and (D). Explain the chemical reactions involved.

A compound (C_(5)H_(8)) reacts with ammoniacal AgNO_(3) to give a white precipitate and reacts with excess of KMnO_(4) solution to give (CH_(3))_(2)CH-COOH . The compound is

An organic compound (A) (C_(9)H_(12)) gave (B) (C_(8) H_(6)O_(4)) on oxidation by alkaline KMnO_(4) (B) on heating does not from anhydride. Also , (B) reacts with Br_(2) in the presence of iron to give only one monobromo-derivative (C)(C_(8)H_(5) BrO_(4)) . WHat are (A), (B) , and (D) ?

Among the following, the number of compounds that can react with PCl_(5) to give POCl_(3) is O_(2) , CO_(2) , SO_(2) , H_(2)O , H_(2)SO_(4) , P_(4)O_(10) .

CENGAGE CHEMISTRY ENGLISH-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Subjective
  1. p-Hydroxybenzaldehyde does not undergo Cannizzaro reaction. Explain.

    Text Solution

    |

  2. Complete the following reaction

    Text Solution

    |

  3. Convert HCHO to glycol in one step only.

    Text Solution

    |

  4. Convert and vice versa.

    Text Solution

    |

  5. Convert benzence to PhCHO in one step only.

    Text Solution

    |

  6. An aromatic kentone (X) has the molecular formula C(10)H(12)O(2). On v...

    Text Solution

    |

  7. A natural compound (A) (C(7)H(6)O) forms an oxime. When (A) is treated...

    Text Solution

    |

  8. An organic compound (A) (C(8)H(14)O) forms an oxime and gives a positi...

    Text Solution

    |

  9. Compound (A) (C(6)H(12)O(2)) on reduction with LiAlH(4) yielded two co...

    Text Solution

    |

  10. Hydrocarbon (X), C(7)H(12), on reaction with boron hydride followed by...

    Text Solution

    |

  11. An organic compound (A) (C(6)H(10)) on reaction with CH(3)MgBr followe...

    Text Solution

    |

  12. An organic compound (A) contaning C, H, and O (16.32%) does not decolo...

    Text Solution

    |

  13. A 0.535 gm mixture of ethanol and acetaldehyde when heated with Fehlin...

    Text Solution

    |

  14. An organic compound (A) contains 79.25% C, 5.66% H, and 15.09% O. It h...

    Text Solution

    |

  15. An organic compound (A) containing 60.12% (C ) and 13.3% H has vapour ...

    Text Solution

    |

  16. Two organic compounds (A) and (B) containing 62.01% C and 10.3% H reac...

    Text Solution

    |

  17. An organic compound (A) (C(5)H(7)OCl) reacts rapidly with ethanol to g...

    Text Solution

    |

  18. An organic compound (A) contains 87.27% C and 13.73% H. Its vapour den...

    Text Solution

    |

  19. An organic compound (A) C(4)H(9)Cl on reacting with aqueous KOH gives ...

    Text Solution

    |

  20. An alkyne with five carbon atoms per molecule when passed through dilu...

    Text Solution

    |