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An acidic compound (A) (C4 H8 O3) loses ...

An acidic compound `(A) (C_4 H_8 O_3)` loses its optical activity on strong heating yielding `(B) (C_4 H_6 O_2)` which reacts readly with `KMnO_4`. `(B)` forms a dervative `( C)` with `SOCl_2` which on reaction with `(CH_3)_2 NH` gives `(D)`. The compound `(A)` on oxidation with dilute chromic acid gives an unstable compound `(E)` which decarboxylates readily to give `(F) (C_3 H_6 O)`. The compound `(F)` gives a hydrocarbon `(G)` on treatment with amalgamated `Zn` and `HCl`. Give the structures of `(A)` to `(G)` with proper reasoning.

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AI Generated Solution

To solve the problem step by step, we will identify the structures of compounds A to G based on the information provided in the question and the reasoning outlined in the video transcript. ### Step 1: Identify Compound (A) Given that compound (A) has the molecular formula \(C_4H_8O_3\) and is optically active, we can deduce the following: - The degree of unsaturation is calculated as: \[ \text{Degree of Unsaturation} = \frac{2C + 2 - H}{2} = \frac{2(4) + 2 - 8}{2} = 1 \] ...
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CENGAGE CHEMISTRY ENGLISH-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Subjective)
  1. Acetyl chloride is hydrolysed rapidly by water, whereas benzoyl chlori...

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  2. Complete the following reactions : (i) H 2 ​ (g)+M m ​ O o ​ (...

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  3. H2Y is the formula of a compound. What is the valency exhibited by Y?

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  4. What is the trend in metallic nature of metals as we go from top to bo...

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  5. (a) Define the term neutralisation equivalent of an acid. (b) Find t...

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  6. Neutralisation of 0.3504 gm of acid (A) requires 27.24 ml of 0.15 M Na...

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  7. Which carboxylic acid (B) (N.E = 52 gm eq^-1) loses CO2 when heated to...

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  8. (a)Define saponification equivalent (S.E) of an ester. (b) When is S...

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  9. The molecular formula of an organic compound is C6H12O6 and the empiri...

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  10. A compound with empirical formula XY2 has vapour density equal to its ...

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  11. An organic compound (A) composed of C, H, and O gives a characteristic...

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  12. An acidic compound (A) (C4 H8 O3) loses its optical activity on strong...

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  13. Write down the structures of the ( E) and (F). .

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  14. Write down the structures of (G) and (H) where (G) is C4 H8 O3. .

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  15. A compound (X) with the molecular formula C6 H10 O4 is a neutral liqui...

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  16. A dibasic organic acid gave the following results on analysis : 0.2496...

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  17. An organic diabasic acid (A) gave the following on analysis : C = 57...

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  18. An organic compound (A) on treatment with ethyl alcohol gives a carbox...

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  19. An organic compound (A) (C5 H8 O3) on heating with soda lime gives (B)...

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