Home
Class 12
CHEMISTRY
An organic compound (A) (C5 H8 O3) on he...

An organic compound `(A) (C_5 H_8 O_3)` on heating with soda lime gives `(B)` which reacts with `HCN` to give `( C)`. The compound `( C)` reacts with thionyl chloride to produce `(D)` which on reaction with `KCN` gives a compound `( E)`. Alkaline hydrolysis of `( E)` gives a salt `(F)` which on heating with soda lime produces `n-butane`. Careful oxidation of `(A)` with dichromate give acetic acid and malonic acid. Give the structures to `(A)` to `(F)` with proper reasoning.

Text Solution

AI Generated Solution

To solve the problem step by step, we will identify the compounds (A) to (F) based on the reactions described and the molecular formula provided. ### Step 1: Identify Compound (A) Given the molecular formula of compound (A) is \(C_5H_8O_3\). We first calculate the degree of unsaturation (DU): \[ DU = \frac{2C + 2 - H}{2} = \frac{2(5) + 2 - 8}{2} = \frac{10 + 2 - 8}{2} = \frac{4}{2} = 2 \] ...
Promotional Banner

Topper's Solved these Questions

  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Linked Comprehension)|34 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Multiple Correct)|34 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples|17 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos

Similar Questions

Explore conceptually related problems

Heating of sodium acetate with soda lime produces

Propyl lithium reacts with ethene to give a compound (A) , which on reaction with methanal followed by acidic hydrolysis gives compound (B) . The compound (B) is :

(A) light blue coloured compound on heating will convert into black (B) which reacts with glucose gives red compound (C) and (A) reacts with ammonium hdyroxide in excess in presence of ammonium sulphate give blue compound (D). What is (A), (B), (C) and (D)?

Boron reacts with oxygen at 700^@C to give (A) . Compound (A) reacts with carbon and dry chloride to give (B) and carbon monoxide. (B) on reduction with LiAlH_(4) gives ( C) along with LiCl and AlCl_(3). ( C) on reaction with ammonia gives (D) . Which on heating gives (E).(C) on reaction with NaH gives (F) . Compound (A) is

Which of the following compound(s) on heating with soda lime gives propane?

A compound (A) of boron react with NMe_(3) to give an adduct (B) which in hydrolysis gives a compound (C) and hydrogen gas. Compound (C) is an acid. Indenfity the compounds A,B and C. Give the reactions involved.

An acidic compound (A) (C_4 H_8 O_3) loses its optical activity on strong heating yielding (B) (C_4 H_6 O_2) which reacts readly with KMnO_4 . (B) forms a dervative ( C) with SOCl_2 which on reaction with (CH_3)_2 NH gives (D) . The compound (A) on oxidation with dilute chromic acid gives an unstable compound (E) which decarboxylates readily to give (F) (C_3 H_6 O) . The compound (F) gives a hydrocarbon (G) on treatment with amalgamated Zn and HCl . Give the structures of (A) to (G) with proper reasoning.

Boron reacts with oxygen at 700^@C to give (A) . Compound (A) reacts with carbon and dry chloride to give (B) and carbon monoxide. (B) on reduction with LiAlH_(4) gives ( C) along with LiCl and AlCl_(3). ( C) on reaction with ammonia gives (D) . Which on heating gives (E).(C) on reaction with NaH gives (F) . Compound (C) is

Boron reacts with oxygen at 700^@C to give (A) . Compound (A) reacts with carbon and dry chloride to give (B) and carbon monoxide. (B) on reduction with LiAlH_(4) gives ( C) along with LiCl and AlCl_(3). ( C) on reaction with ammonia gives (D) . Which on heating gives (E).(C) on reaction with NaH gives (F) . In compound (B) :

When an inorganic compound reacts with SO_2 in aqueous medium produces (A). (A) on reaction with Na_2 CO_3 gives the compound (B) which with sulphur gives a substance (C) used in photography. The compound (C) is.

CENGAGE CHEMISTRY ENGLISH-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Subjective)
  1. Acetyl chloride is hydrolysed rapidly by water, whereas benzoyl chlori...

    Text Solution

    |

  2. Complete the following reactions : (i) H 2 ​ (g)+M m ​ O o ​ (...

    Text Solution

    |

  3. H2Y is the formula of a compound. What is the valency exhibited by Y?

    Text Solution

    |

  4. What is the trend in metallic nature of metals as we go from top to bo...

    Text Solution

    |

  5. (a) Define the term neutralisation equivalent of an acid. (b) Find t...

    Text Solution

    |

  6. Neutralisation of 0.3504 gm of acid (A) requires 27.24 ml of 0.15 M Na...

    Text Solution

    |

  7. Which carboxylic acid (B) (N.E = 52 gm eq^-1) loses CO2 when heated to...

    Text Solution

    |

  8. (a)Define saponification equivalent (S.E) of an ester. (b) When is S...

    Text Solution

    |

  9. The molecular formula of an organic compound is C6H12O6 and the empiri...

    Text Solution

    |

  10. A compound with empirical formula XY2 has vapour density equal to its ...

    Text Solution

    |

  11. An organic compound (A) composed of C, H, and O gives a characteristic...

    Text Solution

    |

  12. An acidic compound (A) (C4 H8 O3) loses its optical activity on strong...

    Text Solution

    |

  13. Write down the structures of the ( E) and (F). .

    Text Solution

    |

  14. Write down the structures of (G) and (H) where (G) is C4 H8 O3. .

    Text Solution

    |

  15. A compound (X) with the molecular formula C6 H10 O4 is a neutral liqui...

    Text Solution

    |

  16. A dibasic organic acid gave the following results on analysis : 0.2496...

    Text Solution

    |

  17. An organic diabasic acid (A) gave the following on analysis : C = 57...

    Text Solution

    |

  18. An organic compound (A) on treatment with ethyl alcohol gives a carbox...

    Text Solution

    |

  19. An organic compound (A) (C5 H8 O3) on heating with soda lime gives (B)...

    Text Solution

    |