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Complete the following reactions. a. P...

Complete the following reactions.
a. `PhNO_(2) overset(Zn+aq.NH_(4)CI)rarr (I)`
b. `p-Me-C_(6)H_(4)NO_(2) overset(As_(2)O_(3)//Aq.NaOH)rarr(II)`
c. `m-Me-C_(6)H_(4)NO_(2) overset(LAH)rarr(III)`

Text Solution

Verified by Experts

(a) (I) `PhNHOH (N`-Phenyl hydroxylamine)
b (II)
c. (III)
d. (IV)
e. (V)
f. (VI) `PhNHNH_(2)` (Phenyl hydrazine)
g. It is an example of Gattermann reaction for making bipphenyls.
h.
i. It is an example of pinacole-type ring expansion via carbocation.
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