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Assertion (A) : Hofmann bromamide reacti...

Assertion (A) : Hofmann bromamide reaction takes place btween an arthide and `Br_2` in basic medium .
Reason (R ). The reaction proceeds by the formation of `(R-overlineN: )` nitrene intremediate.

A

If both (A) and (R ) ar true, and (R ) is the correct explanation of (A).

B

If both (A) and (R ) are true , and (R ) is not the correct explanation of (A).

C

If (A) is true , but (R ) is false .

D

If both (A) and (R ) are false .

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To solve the question regarding the Hofmann bromamide reaction, we will analyze the assertion and reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the Hofmann bromamide reaction takes place between an amide and bromine in a basic medium. - This is indeed true. The Hofmann bromamide reaction involves the reaction of an amide with bromine (Br2) in the presence of a base (like KOH) to produce a primary amine with one less carbon atom. 2. **Mechanism of the Reaction**: - The reaction begins with the deprotonation of the amide nitrogen by the hydroxide ion (OH-) from the basic medium. This forms a negatively charged nitrogen species. - The bromine molecule (Br2) then reacts with this negatively charged nitrogen, forming an electrophile that will lead to the formation of an isocyanate intermediate. 3. **Formation of the Intermediate**: - The intermediate formed during this reaction is not a nitrene but rather an isocyanate (R-N=C=O). This is a key point that distinguishes the assertion from the reason. - The reaction continues with the isocyanate being hydrolyzed to yield a primary amine (RNH2) and carbon dioxide (CO2). 4. **Understanding the Reason**: - The reason states that the reaction proceeds by the formation of a nitrene intermediate. - This is incorrect because the intermediate formed is an isocyanate, not a nitrene. Therefore, the reason is false. 5. **Conclusion**: - The assertion is true, while the reason is false. Thus, the correct answer to the question is that the assertion is true and the reason is false. ### Final Answer: - Assertion (A) is true. - Reason (R) is false. - Therefore, the answer is option C: Assertion true, Reason false.

To solve the question regarding the Hofmann bromamide reaction, we will analyze the assertion and reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the Hofmann bromamide reaction takes place between an amide and bromine in a basic medium. - This is indeed true. The Hofmann bromamide reaction involves the reaction of an amide with bromine (Br2) in the presence of a base (like KOH) to produce a primary amine with one less carbon atom. ...
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