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Discuss the main purpose of vulcanisatio...

Discuss the main purpose of vulcanisation of rubber

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Natural rubber has the folowing disadvantages:
(i)It is soft and sticky and becomes more so at high temperature and brittle atlow temperature.That is why it is used at low temperature range`(280-330K)`where its elasticity maintained.
(ii)It is attacked by oxygen and othe oxidising agents
(iii)It has a high water absorption capacity,low tensile strength ,and low resistance to abrasion.
(iv)It is reactive to organic solvents.
Therefore ,natural rubber is vulcanised by heating it with about`(3-5%)`sulpher at`(373-415K)`.During vulcanisation ,sulphur bridges or the cross-links between polymer chains are introduced.Thus,vulcanised rubber so contained has excellent elasticity over a wide range of temperature,low water absorption capacity,and is resistant to the action of oxygen and other oxidising agents.
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CENGAGE CHEMISTRY ENGLISH-SYNTHETIC AND NATURAL POLYMERS-Exercises Concept Application
  1. Explain the terms polymer and monomer

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  2. What are natural and synthetic polymers? Give two examples of each typ...

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  3. Distinguish between the terms homopolymer and copolymer and give an ex...

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  4. How do you explain the functionality of a monomer?

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  5. Define the term polymerisation.

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  6. Is (NH-CHR-CO)(n), a homopolymer or copolymer?

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  7. In which classes, the polymers classified on the basis of molecular fo...

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  8. How can you differentiate between addition and condensation polymerisa...

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  9. Explain the term copolymerisation and give two examples.

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  10. Write the mechanism of free radical polymerization of ethene.

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  11. Define thermoplastic and ther-mosetting polymers. Give one example of ...

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  12. Write the monomers used for getting the following polymers. (i) Poly...

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  13. Write the name and structure of one of the common initiators used in f...

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  14. How do double bonds in rubber molecules influence their structure and ...

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  15. Discuss the main purpose of vulcanisation of rubber

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  16. What are the monomeric repeating units of Nylon-6 and Nylon-6,6?

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  17. Write the names and structures of the monomers of the following polyme...

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  18. Identify the monomer in the following polymeric structures.

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  19. How is dacron obtained from ethylene glycol and terephthalic acid ?

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  20. What are biodegradable and non-biodegradable detergents ? Give one exa...

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