Home
Class 11
CHEMISTRY
Which of the following Diels- Alder reac...

Which of the following Diels`-` Alder reactions do not take place ?

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following Diels-Alder reactions do not take place, we need to analyze the conditions required for a successful Diels-Alder reaction. The Diels-Alder reaction involves a diene and a dienophile, and there are specific criteria that must be met for the reaction to occur. ### Step-by-Step Solution: 1. **Understand the Diels-Alder Reaction**: The Diels-Alder reaction is a cycloaddition reaction between a conjugated diene and a dienophile. For the reaction to occur, certain conditions must be met. 2. **Identify the Requirements**: - The diene must be in the S-cis conformation. This means that the two double bonds of the diene should be on the same side, allowing for proper overlap with the dienophile. - The diene should typically have electron-donating groups, while the dienophile should have electron-withdrawing groups to facilitate the reaction. - The diene should not be linear; it should be able to adopt a non-linear conformation. 3. **Analyze Each Option**: - **Option A**: If the diene is linear, it cannot adopt the required S-cis conformation, thus the reaction will not take place. - **Option B**: If the diene has S-trans conformation, it cannot participate in the Diels-Alder reaction, as it does not have the necessary orientation for the reaction to occur. - **Option C**: Similar to option B, if the diene is in S-trans conformation, the reaction will not take place. - **Option D**: If the dienophile has electron-withdrawing groups instead of electron-donating groups, the reaction will not occur as the electronic requirements are not met. 4. **Conclusion**: Based on the analysis, all options (A, B, C, and D) do not satisfy the conditions necessary for a Diels-Alder reaction to occur. Therefore, none of the reactions will take place. ### Final Answer: The Diels-Alder reactions that do not take place are **A, B, C, and D**. ---

To determine which of the following Diels-Alder reactions do not take place, we need to analyze the conditions required for a successful Diels-Alder reaction. The Diels-Alder reaction involves a diene and a dienophile, and there are specific criteria that must be met for the reaction to occur. ### Step-by-Step Solution: 1. **Understand the Diels-Alder Reaction**: The Diels-Alder reaction is a cycloaddition reaction between a conjugated diene and a dienophile. For the reaction to occur, certain conditions must be met. 2. **Identify the Requirements**: ...
Promotional Banner

Topper's Solved these Questions

  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise Single Correct Answer Type|62 Videos
  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives(ASSERTION-REASIOING)|4 Videos
  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise linked Comprehension Type|38 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives|13 Videos
  • ALKYNES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Archives - Analytical and Desriptive Type)|4 Videos

Similar Questions

Explore conceptually related problems

Complete the following Deils - Alder reactions.

Which of the following reactions does not take place during leaching for concentration of bauxite ?

Which of the following reactions does not take place during rusting?

The light reaction does not take place in

Which of the following reaction does not take place at cathode ?

In which of the following , Convection of heat does not take place ?

Which of the following reactions does not take place?

Which of the following reactions does not take place?

Which of the following reactions does not take place?

CENGAGE CHEMISTRY ENGLISH-ALKENES AND ALKADIENES-Multiple Correct Answer Type
  1. Which of the following statements is // are wrong ?

    Text Solution

    |

  2. Which of the following statements is/are wrong ?

    Text Solution

    |

  3. Which products are not formed ?

    Text Solution

    |

  4. What other products is // are formed in Question ?

    Text Solution

    |

  5. Text Solution

    |

  6. Which of the following dienes an dienophiles could be used to synthesi...

    Text Solution

    |

  7. Which of the following statements is //are correct.

    Text Solution

    |

  8. underset((A))underset("Propa-1,2-diene")(Coverset(3)(H)(2)=overset(2)(...

    Text Solution

    |

  9. Which of the following statements is // are correct ?

    Text Solution

    |

  10. (C) overset(H(3)O^(+)//H(2)O)(rarr)(E) (D) overset(H(3)O^(+)//H(2)O)...

    Text Solution

    |

  11. Which of the following does not react with aqueous KMnO(4) ?

    Text Solution

    |

  12. Which of the following decolourise(s)Br(2) solution ?

    Text Solution

    |

  13. Which of the following statements is // are correct ?

    Text Solution

    |

  14. Which of the following statements is // are correct ?

    Text Solution

    |

  15. Which of the following Diels- Alder reactions do not take place ?

    Text Solution

    |

  16. Which of the following statements is // are correct ?

    Text Solution

    |

  17. Which of the following has the smallest heat of hydrogenation per mole...

    Text Solution

    |

  18. The numberical values of (N) and (M) are :

    Text Solution

    |

  19. The correct statement(s) concerning the structures E, F and G is/are

    Text Solution

    |

  20. The correct statement(s) about the compound H(3)C(HO)HC-CH=CH-CH(OH)...

    Text Solution

    |