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Assertion: -But-1-ene on reaction with H...

Assertion: -But-1-ene on reaction with HBr in the presence of a peroxide produces 1-bromobutane.
Reason :-It involves the formation of a primary radical.

A

Statement `I` is true, Statement `II` is true, Statement `II` is the correct explanation of Statement `I`.

B

Statement`I` is true, Statement`II` is true, Statement `II` is not the correct explanation of Statement `I`.

C

Statement `I` is true, Statement `II` is false.

D

Statement `I` is false, Statement `II` is true.

Text Solution

Verified by Experts

The correct Answer is:
c

Statement `(I)` is correct but statement `(II)` is incorrect because `1-` butene on reaction with `HBr` in the presence of peroxide produces `1-`promobutane. In this reaction, the intermediate product is a secondary free radical.
i.a. `Ph-overset(O)overset(||)(C)-O-O-overset(O)overset(||)(C)-Phrarr2PhCOO^(*)`
b. `PhC CO^(*)+HBr rarr PhCOOH+Br^(*)`
ii.`CH_(3)CH_(2)CH=CH_(2)+Br^(.)rarr underset(2^(@)"radical")(CH_(3)CH_(2)overset(.)(C)HCH_(2)Br)`
`CH_(3)CH_(2)underset(.)(C)hch_(2)BR+HBr rarrCH_(3).CH_(2)CHCH_(2)Br+Br^(*)`
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