Statement I `: ` Dimethyl sulphide is commonly used for the reduction of an ozonide of compound.
Statement II`:` It reduces the ozonide giving water soluble dimethyl sulphoxide and excess of it evaporates.
Statement I `: ` Dimethyl sulphide is commonly used for the reduction of an ozonide of compound.
Statement II`:` It reduces the ozonide giving water soluble dimethyl sulphoxide and excess of it evaporates.
Statement II`:` It reduces the ozonide giving water soluble dimethyl sulphoxide and excess of it evaporates.
A
Statement `I` is true, Statement `II` is true, Statement `II` is the correct explanation of Statement `I`.
B
Statement`I` is true, Statement`II` is true, Statement `II` is not the correct explanation of Statement `I`.
C
Statement `I` is true, Statement `II` is false.
D
Statement `I` is false, Statement `II` is true.
Text Solution
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The correct Answer is:
To solve the question regarding the statements about dimethyl sulfide and its role in the reduction of ozonides, we can break it down step by step.
### Step-by-Step Solution:
1. **Understanding Ozonides**:
- Ozonides are formed when alkenes react with ozone (O₃). The general reaction can be represented as:
\[
RCH=CHR + O_3 \rightarrow RCH(O)OCR
\]
- This reaction produces an ozonide, which contains a cyclic structure with oxygen.
**Hint**: Remember that ozonides are intermediates formed during the ozonolysis of alkenes.
2. **Role of Dimethyl Sulfide**:
- Dimethyl sulfide (DMS), with the formula (CH₃)₂S, is used as a reducing agent. It can reduce ozonides to yield carbonyl compounds.
- The reaction can be represented as:
\[
RCH(O)OCR + (CH_3)_2S \rightarrow RCHO + (CH_3)_2SO
\]
- Here, DMS reduces the ozonide, resulting in the formation of carbonyl compounds (aldehydes or ketones) and dimethyl sulfoxide (DMSO).
**Hint**: Identify the functional groups involved in the reaction to understand the reduction process.
3. **Formation of Dimethyl Sulfoxide**:
- The product formed from the reaction between DMS and ozonide is dimethyl sulfoxide (DMSO), which is water-soluble.
- The reaction leads to the formation of DMSO and the release of carbonyl compounds.
**Hint**: Consider the solubility properties of the products formed during the reaction.
4. **Evaporation of Excess DMS**:
- Since DMS is volatile, any excess dimethyl sulfide that is not consumed in the reaction will evaporate.
- This property is beneficial as it allows for easier isolation of the desired products (like DMSO and carbonyl compounds).
**Hint**: Think about how the physical properties of a compound (like volatility) can affect the reaction outcome.
5. **Conclusion**:
- Both statements are true:
- **Statement I**: Dimethyl sulfide is commonly used for the reduction of ozonides.
- **Statement II**: It reduces the ozonide to give water-soluble dimethyl sulfoxide, and excess DMS evaporates.
- Therefore, the correct conclusion is that both statements are true, and Statement II explains Statement I.
**Final Answer**: Both Statement I and Statement II are true.
To solve the question regarding the statements about dimethyl sulfide and its role in the reduction of ozonides, we can break it down step by step.
### Step-by-Step Solution:
1. **Understanding Ozonides**:
- Ozonides are formed when alkenes react with ozone (O₃). The general reaction can be represented as:
\[
RCH=CHR + O_3 \rightarrow RCH(O)OCR
...
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