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In which of the following compounds does...

In which of the following compounds does intramolecular `H`-bonding occure?
a. `o`-Nitro phenol
b, `o`-Cresol
c. `o`-Hydrox benzoic acid

Text Solution

AI Generated Solution

To determine which of the given compounds exhibit intramolecular hydrogen bonding, we will analyze each compound step by step. ### Step 1: Understanding Intramolecular Hydrogen Bonding Intramolecular hydrogen bonding occurs when a hydrogen atom covalently bonded to an electronegative atom (like oxygen or nitrogen) forms a bond with another electronegative atom within the same molecule. This typically involves a hydrogen atom attached to an -OH or -NH group and another electronegative atom in close proximity. ### Step 2: Analyzing Ortho-Nitrophenol - **Structure**: Ortho-nitrophenol has a hydroxyl group (-OH) and a nitro group (-NO2) at the ortho position on the benzene ring. - **Hydrogen Bonding**: The hydrogen atom from the -OH group can form a hydrogen bond with the electronegative oxygen atom of the nitro group. ...
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Knowledge Check

  • Which of the following compounds are more acidic than H_(2)O ?

    A
    `CH_(3)-OH`
    B
    `H-overset(overset(O)(||))(C)-OH`
    C
    `CH_(3)-ddot(N)H_(2)`
    D
  • Which of the following has longest C-O bond?

    A
    B
    C
    D
  • Which of the following species shows intramolecular hydrogen bonding ? (A)o-Nitrophenol (B)p- Nitrophenol (C)Benzoic acid (D) Ethanol

    A
    o-Nitrophenol
    B
    p- Nitrophenol
    C
    Benzoic acid
    D
    Ethanol
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