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(A) A(C(7)H(14)) overset(O(3)//Red)(rarr...

(A) `A(C_(7)H_(14)) overset(O_(3)//Red)(rarr)B(C_(3)H_(6)O)+C`
(B) Gives positive Tollens test but negative iodform test.
(C ) Give negative Tollens test but positive iodoform test.
The compound (C ) is:

A

a.

B

b.

C

c.

D

d.Both `(a)` and `(c )`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, let's analyze the information provided and derive the required compound (C). ### Step 1: Identify the structure of compound A - Given that compound A has the formula \(C_7H_{14}\), it is likely an alkene. The simplest structure for an alkene with this formula is heptene. ### Step 2: Understand the ozonolysis reaction - Ozonolysis of alkenes typically results in the formation of carbonyl compounds (aldehydes and/or ketones). When heptene undergoes ozonolysis, it will break down into two products. ### Step 3: Identify the products B and C - The products of ozonolysis will be: - **B**: An aldehyde (which gives a positive Tollens test and a negative iodoform test). - **C**: A ketone (which gives a negative Tollens test and a positive iodoform test). ### Step 4: Analyze the tests - **Tollens test**: Positive for aldehydes and negative for ketones. - **Iodoform test**: Positive for methyl ketones (ketones with the structure \(RCOCH_3\)) and negative for aldehydes. ### Step 5: Determine the structure of compound B - Since B gives a positive Tollens test and a negative iodoform test, it must be an aldehyde. The likely candidate from the ozonolysis of heptene is propanal (\(CH_3CH_2CHO\)). ### Step 6: Determine the structure of compound C - Since C gives a negative Tollens test and a positive iodoform test, it must be a ketone. The likely candidate from the ozonolysis of heptene is butanone (\(CH_3COCH_2CH_3\)). ### Conclusion - Therefore, the compound C is butanone. ### Final Answer The compound C is **butanone**. ---
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(A) A(C_(7)H_(14)) overset(O_(3)//Red)(rarr)B(C_(3)H_(6)O)+C (B) Gives positive Tollens test but negative iodform test. (C ) Give negative Tollens test but positive iodoform test. The compound (B) is:

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(A) A(C_(7)H_(14)) overset(O_(3)//Red)(rarr)B(C_(3)H_(6)O)+C (B) Gives positive Tollens test but negative iodform test. (C ) Give negative Tollens test but positive iodoform test. The compound (B) can be converted to (C ) by using the reagents:

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(A), (B) and (C ) are three non-cylic funtional isomers of a carbonyl compound with molecular formula C_(4)H_(8)O . Isomers (A) and (C ) give positive Tollen's test whereas isomer (B) does not give Tollens' test but gives positive iodoform test. Isomers (A) and (B) on reduction with Zn(Mg) | conc. HCl give the same product (D). (a) Write the structures of (A), (B) ,(C) and (D). (b) Out of (A), (B) and (C ) isomers, which one is least reactive towards addition of HCN ?

Alkene (X) (C_(5)H_(10)) on ozonolysis gives a mixture of two compounds (Y) and (Z). Compound (Y) gives positive Fehling's test and iodoform test. Compound (Z) does not give Fehling's test but give iodoform test. Name the compound formed when Z reacts with Mg - Hg / H_(2)O

CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Linked Comprehension)
  1. (A) A(C(7)H(14)) overset(O(3)//Red)(rarr)B(C(3)H(6)O)+C (B) Gives po...

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  2. (A) A(C(7)H(14)) overset(O(3)//Red)(rarr)B(C(3)H(6)O)+C (B) Gives po...

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  3. (A) A(C(7)H(14)) overset(O(3)//Red)(rarr)B(C(3)H(6)O)+C (B) Gives po...

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  4. (A) A(C(7)H(14)) overset(O(3)//Red)(rarr)B(C(3)H(6)O)+C (B) Gives po...

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  5. (A)(C(8)H(14))underset(Acidic KMnO(4))overset([O])(rarr)(B)+(C )+(D) ...

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  6. (A)(C(8)H(14))underset(Acidic KMnO(4))overset([O])(rarr)(B)+(C )+(D) ...

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  7. (A)(C(8)H(14))underset(Acidic KMnO(4))overset([O])(rarr)(B)+(C )+(D) ...

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  8. (A)(C(8)H(14))underset(Acidic KMnO(4))overset([O])(rarr)(B)+(C )+(D) ...

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  9. (A)(C(8)H(14))underset(Acidic KMnO(4))overset([O])(rarr)(B)+(C )+(D) ...

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  10. The compound (A) is:

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  11. The compound (B) is:

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  12. The compound (C ) is:

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  13. The compound (D) is:

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  14. Text Solution

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  15. (A)(C(9)H(12)O)underset(Hot KMnO(4))overset([O])(rarr) PhCOOH i. (A)...

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  16. (A)(C(9)H(12)O)underset(Hot KMnO(4))overset([O])(rarr) PhCOOH i. (A)...

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  17. (A)(C(9)H(12)O)underset(Hot KMnO(4))overset([O])(rarr) PhCOOH i. (A)...

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  18. (A)(C(9)H(12)O)underset(Hot KMnO(4))overset([O])(rarr) PhCOOH i. (A)...

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  19. The compound (C ) is:

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  20. The compound (F) is:

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