Home
Class 12
CHEMISTRY
Statement 1: Reduction of 3-phenyl prop-...

Statement 1: Reduction of `3`-phenyl prop-2-en-1-al with `LAH` gives 3-phenyl propan-1-ol.
Statement 2: Both the double bond and the aldehyde group of `alpha, beta`-unsaturated aldehydes are reduced by `LAH`.

A

a.Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1.

B

b.Statement 1 and Statement 2 are true and Statement 2 is not the correct explanation of Statement 1.

C

c.Statement 1 is true and statement 2 is false.

D

d.Statement 1 is false and statement 2 is false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze both statements regarding the reduction of 3-phenyl prop-2-en-1-al with lithium aluminum hydride (LAH) and determine their validity step by step. ### Step 1: Understand the Compound The compound in question is 3-phenyl prop-2-en-1-al. It has the following structure: - The aldehyde group (-CHO) is located at the first carbon. - The double bond (C=C) is between the second and third carbons. - A phenyl group (C6H5) is attached to the third carbon. ### Step 2: Identify the Reducing Agent Lithium aluminum hydride (LAH) is a strong reducing agent. It is capable of reducing: - Aldehydes and ketones to their corresponding alcohols. - Alkenes to alkanes. ### Step 3: Analyze Statement 1 Statement 1 claims that the reduction of 3-phenyl prop-2-en-1-al with LAH gives 3-phenyl propan-1-ol. - When LAH is applied to the compound, it will reduce the aldehyde group to an alcohol, converting it from -CHO to -CH2OH. - Additionally, the double bond (C=C) between the second and third carbons will be reduced to a single bond (C-C). The resulting structure will be: - The aldehyde becomes a primary alcohol (-CH2OH). - The double bond is saturated, resulting in a fully saturated carbon chain. Thus, the final product is indeed 3-phenyl propan-1-ol. ### Step 4: Analyze Statement 2 Statement 2 states that both the double bond and the aldehyde group of alpha, beta-unsaturated aldehydes are reduced by LAH. - In the case of 3-phenyl prop-2-en-1-al, the compound is an alpha, beta-unsaturated aldehyde. - LAH will reduce both the aldehyde group and the double bond, as previously discussed. ### Conclusion Both statements are correct: - Statement 1 is true because the reduction yields 3-phenyl propan-1-ol. - Statement 2 is true because LAH reduces both the double bond and the aldehyde group in alpha, beta-unsaturated aldehydes. ### Final Answer Both statements are correct, and Statement 2 is the correct explanation for Statement 1. Therefore, the answer is option A. ---

To solve the problem, we will analyze both statements regarding the reduction of 3-phenyl prop-2-en-1-al with lithium aluminum hydride (LAH) and determine their validity step by step. ### Step 1: Understand the Compound The compound in question is 3-phenyl prop-2-en-1-al. It has the following structure: - The aldehyde group (-CHO) is located at the first carbon. - The double bond (C=C) is between the second and third carbons. - A phenyl group (C6H5) is attached to the third carbon. ...
Promotional Banner

Topper's Solved these Questions

  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise Archives (Subjective)|26 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise SUBJECTIVE TYPE|4 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercise (Single Correct)|90 Videos
  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Viva Voce Questions And Part-C (Analysis Of Cations)|42 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 1.2 (Objective)|9 Videos

Similar Questions

Explore conceptually related problems

Convert propane into prop-2-en-1-ol

Statement-1:Reduction of But-2-yne of Na/liq. NH_3 gives trans-But-2-ene. Statement-2: It is an example of 'anti' addition.

Statement-1:When 3-Chlorobut-1-ene react H_2O then give four products. Statement-2:Intermediate is carbocation and it show resonance and recemisation.

Statement-1: Al(OH)_(3) is amphoteric in nature. Statement-2: It cannot be used as an antacid.

Statement - 1 : Al is used as a reducing agent in aluminothermite process. And Statement - 2 : Al has a lower melting point than Fe, Cr and Mn.

Statement-1: Reflection of the point (-3, 2) in the line x + y = 0 is (-2, 3).Statement-2: The reflection of a point P(alpha,beta) in the line ax+by+c=0 is the point Q(alpha', beta') if ((alpha+alpha')/2, (beta+beta')/2) lies on the line

Statement I Reflection of the point (5,1) in the line x+y=0 is (-1,-5) Statement II Reflection of a point P(alpha,beta) in the line ax+by+c= 0 is Q (alpha',beta' ) " if " ((alpha +alpha')/2 ,(beta +beta' )/2) lies on the line .

Statement-1: Formation of cyclic acetal is entropically favourable. Statemen-2: PCC converts primary alcohol into aldehydes. Statement-3: Aliphatic alcohols are practically insoluble in aqueous NaOH.

Statement 1. If a,b,c and K are constant quantities and alpha, beta, gamma are variables satisfying the relation a tan alpha+b tan beta+c tan gamma=K, then the maximum value of tan^2alpha+tan^2beta+tan^2gamma= K^2/(a^2+b^2+c^2), Statement 2: If a_1, a_2, a_3 and b_1, b_2, b_3 are real, then (a_1^2+a_2^2+a_3^2)(b_1^2+b_2^2+b_3^2)ge(a_1b_1+a_2b_2+a_3b_3)^2 (A) Both Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1 (B) Both Statement 1 and Statement 2 are true and Statement 2 is not the correct explanation of Statement 1 (C) Statement 1 is true but Statement 2 is false. (D) Statement 1 is false but Statement 2 is true

Statement 1. cos^-1 x-sin^-1 (x/2+sqrt((3-3x^2))/2)=- pi/3, where 1/2 lexle1 , Statement 2. 2sin^-1 x=sin^-1 2x sqrt(1-x^2), where - 1/sqrt(2)lexle1/sqrt(2). (A) Both Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1 (B) Both Statement 1 and Statement 2 are true and Statement 2 is not the correct explanatioin of Statement 1 (C) Statement 1 is true but Statement 2 is false. (D) Statement 1 is false but Statement 2 is true