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Statement 1: Diisopropyl ketone on react...

Statement 1: Diisopropyl ketone on reaction with isopropyl magnesium bromide followed by hydrolysis gives `2^(@)` alcohol.
Statement 2: Grignard reagent acts as a reducing agent.

A

a.Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1.

B

b.Statement 1 and Statement 2 are true and Statement 2 is not the correct explanation of Statement 1.

C

c.Statement 1 is true and statement 2 is false.

D

d.Statement 1 is false and statement 2 is false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both statements provided and provide a step-by-step explanation of the chemical reaction involved. ### Step 1: Understanding Diisopropyl Ketone Diisopropyl ketone (also known as 3-pentanone) has the following structure: ``` CH3 | CH3-C-CH2 || O ``` In this structure, the carbonyl group (C=O) is attached to a carbon atom that is also bonded to two isopropyl groups (CH(CH3)2). ### Step 2: Reaction with Isopropyl Magnesium Bromide Isopropyl magnesium bromide (a Grignard reagent) has the following structure: ``` CH3 | CH3-C-MgBr ``` When diisopropyl ketone reacts with isopropyl magnesium bromide, the Grignard reagent acts as a nucleophile. The carbonyl carbon of the ketone is electrophilic and will react with the nucleophilic carbon of the Grignard reagent. ### Step 3: Nucleophilic Attack The nucleophilic carbon from the Grignard reagent attacks the carbonyl carbon, resulting in the formation of a tetrahedral intermediate. This intermediate can be represented as: ``` CH3 | CH3-C-O-MgBr | CH2 ``` ### Step 4: Hydrolysis Upon hydrolysis (addition of water), the magnesium bromide leaves, and a hydroxyl group (-OH) is formed. The final product is a secondary alcohol: ``` CH3 | CH3-C-OH | CH2 ``` This compound is diisopropyl alcohol, which is a secondary alcohol because the carbon attached to the hydroxyl group is bonded to two other carbon atoms. ### Step 5: Conclusion on Statements - **Statement 1**: Diisopropyl ketone on reaction with isopropyl magnesium bromide followed by hydrolysis gives a secondary alcohol. This statement is **correct**. - **Statement 2**: Grignard reagent acts as a reducing agent. This statement is also **correct** because it provides a hydride ion (H-) that reduces the ketone to an alcohol. ### Final Answer Both statements are correct, and statement 2 provides the correct explanation for statement 1. Therefore, the answer is option A. ---

To solve the question, we will analyze both statements provided and provide a step-by-step explanation of the chemical reaction involved. ### Step 1: Understanding Diisopropyl Ketone Diisopropyl ketone (also known as 3-pentanone) has the following structure: ``` CH3 | ...
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