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An organic compound (A), C(8)H(4) O(3) i...

An organic compound `(A), C_(8)H_(4) O_(3)` in dry benzene in the presene of anhydorus `AlCl_(3)` gives compound `(B)`. Compound `(B)` on treatment with `PCl_(5)` followed by reaction with `H_(2)//Pd (BaSO_(4))` gives compound `(C)` which on reaction with hydrazine gives a cyclised compound `(D),(C_(14) H_(10) N_(2))` Idenyify `(A),(B),(C)` and `(D)`. Explain the formation of `(D)` from `(C)`.

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To solve the problem step by step, we will identify the compounds A, B, C, and D based on the given reactions and their molecular formulas. ### Step 1: Identify Compound (A) Given that compound (A) has the formula \( C_8H_4O_3 \), we can deduce its structure. The presence of three oxygen atoms suggests that it might contain a carboxylic acid or an ester group. A possible structure for compound (A) is: - **Compound (A)**: 1,2-benzenedicarboxylic acid (Phthalic acid) ### Step 2: Reaction of Compound (A) to form Compound (B) ...
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CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Subjective
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  3. The ion that cannot undergo disproportionation is :

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  6. An organic compound (A), C(8)H(4) O(3) in dry benzene in the presene ...

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  7. Three isomeric hydrocations C(9) H(12) [(A),(B),(C)] oxide to C(9) H(...

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  8. An organtiic compound (A) contains C = 92.3% and H = 7.7% Its vapour d...

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  9. An aromatic hydrocarbobn (A) containing C = 91.3% and H = 8.7% on tre...

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  10. The compound C8H9Cl(A) on treatments with KCN followed by hydrolysis g...

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  11. ON disuphonatioon followed by fusion with NaOH an dacidificant, an aro...

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  12. The compoiund A is xylene. On sulphonation, it gives only one product...

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  13. Compound (A)(C(8)H(12)) on oxidation gives an acid B(C(4)H(6)O(2)). On...

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  14. A hydrocarbon C(9) H(10) (A) rapidly decolourises cold aquous permanga...

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  16. When boromobenze is monochlorinated. Two isomeric compounds (A) and (B...

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