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The compound C8H9Cl(A) on treatments wit...

The compound `C_8H_9Cl(A)` on treatments with KCN followed by hydrolysis gives `C_9H_10O_2(B)`.Ammonium salt of B on dry distillation yields C.Which reacts with alkaline solution of bromine to gives `C_8H_11N`.(D),Another compound E `(C_6H_10O)` is obtained by the action of nitrous acid on D. or by the action of aquouspotash on A,E on oxidation gives `F(C_8H_10O)` Which gives the inner anhydride G on heating.
The compound D is reaction with `CHCl_3+NaOH` gives a compound H.The structure of H.

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`D.U` in `(A) = ((2n_(C) + 2) + 2_(Cl) - n_(H))/(2)`
`= ((2xx8+2)+1-9)/(2) = 5^(@)`
`5 D.U` and `(C:H = 1:1)` suggest benzene ring in `(A)`, with two `(Me)` groups or one `(Et)` group.
Reaction with `KCN` shows that `(A)` contain `1^(@) RCl` group (i.e., it contains `(-CH_(2)Cl)` group in the side chain and one `(Me)` group in the ring).
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Formation of `(G)`, an anjydride shows that `(Me)` groupas is at ortho-postion. orthos-diacid froms anhydride.
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The compound C_8H_9Cl(A) on treatments with KCN followed by hydrolysis gives C_9H_10O_2(B) .Ammonium salt of B on dry distillation yields C.Which reacts with alkaline solution of bromine to gives C_8H_11N .(D),Another compound E (C_6H_10O) is obtained by the action of nitrous acid on D. or by the action of aquouspotash on A,E on oxidation gives F(C_8H_10O) Which gives the inner anhydride G on heating. The compound D is reaction with CHCl_3+NaOH gives a compound H. The compound A on reaction with AgCN gives :

The compound C_8H_9Cl(A) on treatments with KCN followed by hydrolysis gives C_9H_10O_2(B) .Ammonium salt of B on dry distillation yields C.Which reacts with alkaline solution of bromine to gives C_8H_11N .(D)Another compound E is obtained by the action of nitrous acid on D. E on oxidation gives F which gives the inner anhydride G on heating. The Compound A is :

Compound (A) C_(8)H_(9)Br . Gives a white precipitate when warmed with alcoholic AgNO_(3) . Oxidation of (A) gives an acid (B). C_(8)H_(6)O_(4) . (B) easily forms anhydride on heating. Identify the compound (A)

Compound (A) C_(8)H_(9)Br . Gives a white precipitate when warmed with alcoholic AgNO_(3) . Oxidation of (A) gives an acid (B). C_(8)H_(6)O_(4) . (B) easily forms anhydride on heating. Identify the compound (A)

Acetoisonitrile on reaction with C_2 H_5 MgBr followed by hydrolysis, gives compound (A) , which one further hydrolysis gives (B) and ( C) . (B) and ( C) are :

A compound D(C_(8)H_(10)O) upon treatement with alkaline solution of iodine gives a yellow precipitate. The fibtrate on acidification gives a white solid E(C_(7)H_(6)O_(2)) . Write the structures of D,E .

A compound (A) C_(5)H_(10) Cl_(2) on hydrolysis gives C_(5)H_(10)O which reacts with NH_(2)OH , forms iodoform but does not give Fehling test (A) is :

Boron reacts with oxygen at 700^@C to give (A) . Compound (A) reacts with carbon and dry chloride to give (B) and carbon monoxide. (B) on reduction with LiAlH_(4) gives ( C) along with LiCl and AlCl_(3). ( C) on reaction with ammonia gives (D) . Which on heating gives (E).(C) on reaction with NaH gives (F) . Compound (A) is

An organic compound (A) (C_5 H_8 O_3) on heating with soda lime gives (B) which reacts with HCN to give ( C) . The compound ( C) reacts with thionyl chloride to produce (D) which on reaction with KCN gives a compound ( E) . Alkaline hydrolysis of ( E) gives a salt (F) which on heating with soda lime produces n-butane . Careful oxidation of (A) with dichromate give acetic acid and malonic acid. Give the structures to (A) to (F) with proper reasoning.

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