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Which of the following reactions are bot...

Which of the following reactions are both sterospecific and steroselective ?

A

`SN^(1)`

B

`SN^(2)`

C

`E1`

D

`E2`

Text Solution

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The correct Answer is:
To determine which reactions are both stereospecific and stereoselective, we need to analyze the characteristics of the reactions in question. ### Step-by-Step Solution: 1. **Understanding Stereospecificity**: - A reaction is stereospecific if the configuration of the reactant determines the configuration of the product. This means that a specific stereoisomer of the reactant will lead to a specific stereoisomer of the product. - Example: In an SN2 reaction, the nucleophile attacks from the backside of the leaving group, leading to inversion of configuration. 2. **Understanding Stereoselectivity**: - A reaction is stereoselective if it preferentially forms one stereoisomer over others when multiple stereoisomers are possible. - Example: In an E2 elimination reaction, the base preferentially removes the more stable β-hydrogen, leading to the formation of the more stable alkene (Zaitsev's rule). 3. **Analyzing SN2 Reaction**: - SN2 reactions are both stereospecific and stereoselective. The nucleophile attacks from the opposite side of the leaving group, leading to inversion of configuration (stereospecific). Additionally, if there are multiple possible products, the reaction will favor the formation of one stereoisomer (stereoselective). 4. **Analyzing E2 Reaction**: - E2 reactions are also both stereospecific and stereoselective. The base removes a specific β-hydrogen, leading to the formation of a particular alkene (stereospecific). Furthermore, the reaction tends to form the more stable alkene product (stereoselective). 5. **Conclusion**: - Based on the analysis, both SN2 and E2 reactions exhibit characteristics of being stereospecific and stereoselective. Therefore, the correct answers are the reactions corresponding to SN2 and E2. ### Final Answer: The reactions that are both stereospecific and stereoselective are **SN2 and E2**.

To determine which reactions are both stereospecific and stereoselective, we need to analyze the characteristics of the reactions in question. ### Step-by-Step Solution: 1. **Understanding Stereospecificity**: - A reaction is stereospecific if the configuration of the reactant determines the configuration of the product. This means that a specific stereoisomer of the reactant will lead to a specific stereoisomer of the product. - Example: In an SN2 reaction, the nucleophile attacks from the backside of the leaving group, leading to inversion of configuration. ...
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CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Multiple Correct
  1. Consider the following compound: Which of the following staements...

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  2. Consider the following reactiions: Which of the staements are cor...

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  3. Which of the following reactions are both sterospecific and steroselec...

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  4. Which of the following reactions(s) is/are both non-sterospecific but ...

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  5. Which of the following reactions(s) is/are sterospecific but non-stero...

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  6. Which of the following reaction(s) is/are neither sterospecific nor st...

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  7. The first steps of SN^(1) and SN^(2) recatiosns are, respectively

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  8. Which of the following staements are correct about ElcB reaction ?

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  9. In which fo the following reactions is the correct major product forme...

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  10. Which of the following syntheses could not be doen without involving b...

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  11. Which of the following side chain reaction/s can be used to reduce th...

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  12. In the following reactions: Which of the following staements a...

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  13. Which are the sources of phenol?

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  14. Which contenet (s) of middle oil separate on cooling?

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  15. Sulfanillic acid at pH = 2 and 12 exists as....and migrates towards......

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  16. Consider the following reactions: I. C(2)H(5) - I + NH(3) rarr C(2) ...

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  17. In which of the above reactions does the rate fo SN^(2) reactions dec...

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  18. Consider the folliwng reactions: I. Me(3)C - Br underset(SN^(1))over...

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  19. Which benzene sulphonic acid and p-nitrophenol are treated with NaHCO3...

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  20. The decreasing order of pK(a) value of the folliwng is:

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