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Which of the following reactions(s) is/a...

Which of the following reactions(s) is/are sterospecific but non-steroselcetive?

A

`SN^(2)`

B

`E1`

C

`E2`

D

`ElcB`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following reactions are stereospecific but not stereoselective, we will analyze the reactions: SN2, E1, E2, and E1CV. ### Step-by-Step Solution: 1. **Understanding Stereospecificity and Stereoselectivity**: - **Stereospecificity**: A reaction is stereospecific if the configuration of the starting material determines the configuration of the product. This means that a specific stereoisomer of the reactant will lead to a specific stereoisomer of the product. - **Stereoselectivity**: A reaction is stereoselective if it preferentially forms one stereoisomer over another from a mixture of stereoisomers. 2. **Analyzing SN2 Reaction**: - The SN2 reaction is stereospecific because it involves a backside attack on the substrate, leading to inversion of configuration. However, it is also stereoselective because it selectively forms one stereoisomer from a chiral substrate. - **Conclusion**: SN2 is not the answer. 3. **Analyzing E1 Reaction**: - The E1 reaction involves the formation of a carbocation intermediate. While the formation of the carbocation is specific, the elimination step can lead to a mixture of products (both E and Z isomers). - **Conclusion**: E1 is not stereospecific as it does not lead to a specific stereoisomer. 4. **Analyzing E2 Reaction**: - The E2 reaction is stereospecific because it requires anti-periplanar geometry for the elimination to occur. However, it can also lead to the formation of multiple stereoisomers depending on the substrate and the elimination pathway. - **Conclusion**: E2 is not the answer as it is also stereoselective. 5. **Analyzing E1CV Reaction**: - The E1CV (Elimination Unimolecular Conjugate Base) reaction is stereospecific because the initial step involves the loss of a beta-hydrogen to form a specific carbocation. However, the subsequent steps can lead to a mixture of products, including different stereoisomers (enantiomers or diastereomers). - **Conclusion**: E1CV is stereospecific but not stereoselective. ### Final Answer: The reaction that is stereospecific but not stereoselective is **E1CV**.

To determine which of the following reactions are stereospecific but not stereoselective, we will analyze the reactions: SN2, E1, E2, and E1CV. ### Step-by-Step Solution: 1. **Understanding Stereospecificity and Stereoselectivity**: - **Stereospecificity**: A reaction is stereospecific if the configuration of the starting material determines the configuration of the product. This means that a specific stereoisomer of the reactant will lead to a specific stereoisomer of the product. - **Stereoselectivity**: A reaction is stereoselective if it preferentially forms one stereoisomer over another from a mixture of stereoisomers. ...
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CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Multiple Correct
  1. Which of the following reactions are both sterospecific and steroselec...

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  2. Which of the following reactions(s) is/are both non-sterospecific but ...

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  3. Which of the following reactions(s) is/are sterospecific but non-stero...

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  4. Which of the following reaction(s) is/are neither sterospecific nor st...

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  5. The first steps of SN^(1) and SN^(2) recatiosns are, respectively

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  6. Which of the following staements are correct about ElcB reaction ?

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  7. In which fo the following reactions is the correct major product forme...

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  8. Which of the following syntheses could not be doen without involving b...

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  9. Which of the following side chain reaction/s can be used to reduce th...

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  10. In the following reactions: Which of the following staements a...

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  11. Which are the sources of phenol?

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  12. Which contenet (s) of middle oil separate on cooling?

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  13. Sulfanillic acid at pH = 2 and 12 exists as....and migrates towards......

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  14. Consider the following reactions: I. C(2)H(5) - I + NH(3) rarr C(2) ...

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  15. In which of the above reactions does the rate fo SN^(2) reactions dec...

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  16. Consider the folliwng reactions: I. Me(3)C - Br underset(SN^(1))over...

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  17. Which benzene sulphonic acid and p-nitrophenol are treated with NaHCO3...

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  18. The decreasing order of pK(a) value of the folliwng is:

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  19. Among the following, which is/are correct?

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  20. Which of the following will give Hofamann alkene?

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