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Which of the following reaction(s) is/ar...

Which of the following reaction(s) is/are neither sterospecific nor steroselective?

A

`SN^(1)`

B

`SN^(2)`

C

`E2`

D

`ElcB`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following reactions is neither stereospecific nor stereoselective, we will analyze each reaction type: SN1, SN2, E2, and E1. ### Step-by-Step Solution: 1. **Understanding Stereospecific and Stereoselective:** - **Stereospecific Reactions:** These reactions produce a specific stereoisomer from a specific stereoisomeric reactant. In other words, the configuration of the reactant determines the configuration of the product. - **Stereoselective Reactions:** These reactions favor the formation of one stereoisomer over others, but do not exclusively produce one type. 2. **Analyzing SN1 Reaction:** - The SN1 reaction involves a two-step mechanism where the substrate first forms a carbocation intermediate. - The nucleophile can attack the carbocation from either side (front or back), leading to the formation of both enantiomers. - Since the nucleophile can attack from both sides, the reaction is **not stereospecific**. - Additionally, because it produces a mixture of enantiomers, it is also **not stereoselective**. 3. **Analyzing SN2 Reaction:** - The SN2 reaction involves a single concerted step where the nucleophile attacks the substrate from the opposite side of the leaving group. - This results in inversion of configuration, making it **stereospecific**. 4. **Analyzing E2 Reaction:** - The E2 reaction is a concerted elimination reaction where the base abstracts a proton while the leaving group departs. - Depending on the geometry of the substrate, it can lead to the formation of specific stereoisomers, making it **stereoselective**. 5. **Analyzing E1 Reaction:** - The E1 reaction also involves a carbocation intermediate similar to SN1. The base then abstracts a proton from the carbocation. - Since the base can attack from either side, it does not have a specific stereochemical outcome, making it **not stereospecific**. - However, it can lead to the formation of a mixture of products, which may or may not favor one stereoisomer, so it can be considered **stereoselective** depending on the substrate. ### Conclusion: From the analysis, the only reaction that is neither stereospecific nor stereoselective is the **SN1 reaction**. ### Final Answer: **SN1 is the reaction that is neither stereospecific nor stereoselective.** ---

To determine which of the following reactions is neither stereospecific nor stereoselective, we will analyze each reaction type: SN1, SN2, E2, and E1. ### Step-by-Step Solution: 1. **Understanding Stereospecific and Stereoselective:** - **Stereospecific Reactions:** These reactions produce a specific stereoisomer from a specific stereoisomeric reactant. In other words, the configuration of the reactant determines the configuration of the product. - **Stereoselective Reactions:** These reactions favor the formation of one stereoisomer over others, but do not exclusively produce one type. ...
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CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Multiple Correct
  1. Which of the following reactions are both sterospecific and steroselec...

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  2. Which of the following reactions(s) is/are both non-sterospecific but ...

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  3. Which of the following reactions(s) is/are sterospecific but non-stero...

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  4. Which of the following reaction(s) is/are neither sterospecific nor st...

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  5. The first steps of SN^(1) and SN^(2) recatiosns are, respectively

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  6. Which of the following staements are correct about ElcB reaction ?

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  7. In which fo the following reactions is the correct major product forme...

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  8. Which of the following syntheses could not be doen without involving b...

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  9. Which of the following side chain reaction/s can be used to reduce th...

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  10. In the following reactions: Which of the following staements a...

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  11. Which are the sources of phenol?

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  12. Which contenet (s) of middle oil separate on cooling?

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  13. Sulfanillic acid at pH = 2 and 12 exists as....and migrates towards......

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  14. Consider the following reactions: I. C(2)H(5) - I + NH(3) rarr C(2) ...

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  15. In which of the above reactions does the rate fo SN^(2) reactions dec...

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  16. Consider the folliwng reactions: I. Me(3)C - Br underset(SN^(1))over...

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  17. Which benzene sulphonic acid and p-nitrophenol are treated with NaHCO3...

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  18. The decreasing order of pK(a) value of the folliwng is:

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  19. Among the following, which is/are correct?

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  20. Which of the following will give Hofamann alkene?

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