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Which of the following staements are cor...

Which of the following staements are correct about `ElcB` reaction ?

A

It proceeds via the formation of carbanion intermediate.

B

Strong `EWG` and poor leaving groups favour the reaction.

C

It is a unimolecular reaction with secound order kinetics.

D

When `D` is incorporated in the staring material by the solvent `EtOD` and the reaction is interupted before completion, no `D` is found either in the substrare or in the product.

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The correct Answer is:
To determine which statements are correct about the E1CB (Elimination Unimolecular Conjugate Base) reaction, let's analyze the characteristics and steps involved in this reaction mechanism. ### Step-by-Step Solution: 1. **Understand the E1CB Mechanism**: - The E1CB mechanism involves the formation of a conjugate base as an intermediate. This reaction typically requires a strong base and a poor leaving group. 2. **Identify the Steps in the Reaction**: - **Step 1**: A strong base abstracts a proton (H⁺) from the beta carbon, leading to the formation of a conjugate base (carbanion). - **Step 2**: The poor leaving group departs, resulting in the formation of an alkene. 3. **Evaluate the Statements**: - **Statement A**: "The reaction requires a strong base and a poor leaving group." - This statement is correct. The E1CB mechanism indeed requires a strong base to remove a proton and a poor leaving group for the reaction to proceed. - **Statement B**: "Strong electron-withdrawing groups and poor leaving groups favor the reaction." - This statement is also correct. Electron-withdrawing groups increase the acidity of the hydrogen on the beta carbon, making it easier for the base to abstract it, thus favoring the reaction. - **Statement C**: "It is a unimolecular reaction." - This statement is correct as well. The rate-determining step involves only one molecule (the substrate), making it unimolecular. - **Statement D**: "When deuterium is incorporated in the starting material, no deuterium is found in the substrate or in the product." - This statement is incorrect. If deuterium is present in the starting material, it can be found in the product as well, assuming the reaction proceeds to completion. 4. **Conclusion**: - The correct statements about the E1CB reaction are A, B, and C. Statement D is incorrect. ### Final Answer: The correct statements about the E1CB reaction are: - A: Correct - B: Correct - C: Correct - D: Incorrect Thus, the answer is A, B, and C are correct.

To determine which statements are correct about the E1CB (Elimination Unimolecular Conjugate Base) reaction, let's analyze the characteristics and steps involved in this reaction mechanism. ### Step-by-Step Solution: 1. **Understand the E1CB Mechanism**: - The E1CB mechanism involves the formation of a conjugate base as an intermediate. This reaction typically requires a strong base and a poor leaving group. 2. **Identify the Steps in the Reaction**: ...
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CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Multiple Correct
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  2. Which of the following reactions(s) is/are both non-sterospecific but ...

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  3. Which of the following reactions(s) is/are sterospecific but non-stero...

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  4. Which of the following reaction(s) is/are neither sterospecific nor st...

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  5. The first steps of SN^(1) and SN^(2) recatiosns are, respectively

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  6. Which of the following staements are correct about ElcB reaction ?

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  7. In which fo the following reactions is the correct major product forme...

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  8. Which of the following syntheses could not be doen without involving b...

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  9. Which of the following side chain reaction/s can be used to reduce th...

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  10. In the following reactions: Which of the following staements a...

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  11. Which are the sources of phenol?

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  12. Which contenet (s) of middle oil separate on cooling?

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  13. Sulfanillic acid at pH = 2 and 12 exists as....and migrates towards......

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  14. Consider the following reactions: I. C(2)H(5) - I + NH(3) rarr C(2) ...

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  15. In which of the above reactions does the rate fo SN^(2) reactions dec...

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  16. Consider the folliwng reactions: I. Me(3)C - Br underset(SN^(1))over...

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  17. Which benzene sulphonic acid and p-nitrophenol are treated with NaHCO3...

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  18. The decreasing order of pK(a) value of the folliwng is:

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  19. Among the following, which is/are correct?

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  20. Which of the following will give Hofamann alkene?

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