Home
Class 12
CHEMISTRY
Consider the following reactions: I. C...

Consider the following reactions:
` I. C_(2)H_(5) - I + NH_(3) rarr C_(2) H_(5) N^(o+)H_(3) + I^(o-)`
II. `C_(2)H_(5) - I + ddot(P)H_(3) rarr C_(2)H_(5) P^(o+)H_(5)` +` I^(o-)`
III. `C_(2)H_(5) - I + EtO^(o-) rarr C_(2) H_(5) - OEt + I^(o-)`
IV. `Me - overset(o+)(S) - Me_(2) + O^(o-)H rarr Me-OH + Me_(2)S`
In which of the above reactions does the rate of `SN^(2)` reactions increases with increase in solvent polarity?

A

`(I)`

B

`(II)`

C

`(III)`

D

`(IV)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine in which of the given reactions the rate of SN2 reactions increases with an increase in solvent polarity, we need to analyze each reaction based on the nature of the nucleophiles and the presence of charged species. ### Step-by-Step Solution: 1. **Understanding SN2 Reactions**: - SN2 (Substitution Nucleophilic Bimolecular) reactions are characterized by a single transition state and involve a nucleophile attacking an electrophile, leading to the displacement of a leaving group. - The rate of SN2 reactions is influenced by the polarity of the solvent, especially when charged species are involved. 2. **Analyzing Each Reaction**: - **Reaction I**: \[ C_2H_5 - I + NH_3 \rightarrow C_2H_5N^{o+}H_3 + I^{o-} \] - Here, NH3 is a neutral nucleophile. Increasing solvent polarity will stabilize the transition state and potentially increase the reaction rate. - **Reaction II**: \[ C_2H_5 - I + PH_3 \rightarrow C_2H_5P^{o+}H_5 + I^{o-} \] - Similar to Reaction I, PH3 is also a neutral nucleophile. Thus, increasing solvent polarity may also increase the reaction rate. - **Reaction III**: \[ C_2H_5 - I + EtO^{o-} \rightarrow C_2H_5 - OEt + I^{o-} \] - Here, EtO^- is a charged nucleophile. Increasing solvent polarity would stabilize the charged species and decrease the reaction rate. - **Reaction IV**: \[ Me - (S) - Me_2 + O^{o-}H \rightarrow Me-OH + Me_2S \] - In this reaction, O^- is also a charged nucleophile. Similar to Reaction III, increasing solvent polarity would decrease the reaction rate. 3. **Conclusion**: - From the analysis, we find that the reactions where the nucleophile is neutral (Reactions I and II) would see an increase in the rate of SN2 reactions with increasing solvent polarity. - Therefore, the reactions that fit the criteria are **Reaction I and Reaction II**. ### Final Answer: The rate of SN2 reactions increases with an increase in solvent polarity in **Reactions I and II**.

To determine in which of the given reactions the rate of SN2 reactions increases with an increase in solvent polarity, we need to analyze each reaction based on the nature of the nucleophiles and the presence of charged species. ### Step-by-Step Solution: 1. **Understanding SN2 Reactions**: - SN2 (Substitution Nucleophilic Bimolecular) reactions are characterized by a single transition state and involve a nucleophile attacking an electrophile, leading to the displacement of a leaving group. - The rate of SN2 reactions is influenced by the polarity of the solvent, especially when charged species are involved. ...
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct Answers Type|15 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct Answer Type|28 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Linked Compreshension Type|11 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

Complete the following reaction: (i) Cl_(2) + H_(2)O rarr (ii) XeF_(6) + 3H_(2)O rarr

Complete the following reactions: (i) C_(2) H_(4) + O_(2) to (ii) 4Al + 3 O_(2) to

Complete the following reactions (i) O_(2)^(2-)+H_(2)O rarr (ii) O_(2)^(-) +H_(2)O rarr

Complete the following reactions (a) XeF_(4) + H_(2)O rarr (b ) XeF_(6) + H_(2) rarr (c) XeF_(6) + H_(2)O rarr (d) XeF_(6) + NH_(3) rarr

Name the following reaction. C_(6)H_(5)-C-=N overset(SnCl_(2)+HCl)rarr C_(6)H_(5)-CH=N^(o+)H_(2)]Cl^(Θ) overset(H_(2)O)rarr C_(6)H_(5)CHO+NH_(3)

The products of the following chemical reactions are (i) C_(2)H_(5)NH_(2) + C_(6)H_(5)SO_(2)Cl to (ii) C_(2)H_(5)NH_(2) + HNO_(2)overset(H_2O)(rarr)

Predict the products of the following reactions: (i) CH_(3)-CH_(2)-CH_(2)-O-CH_(3)+HBr rarr (iv) (CH_(3))_(3)C-OC_(2)H_(5)overset(HI)rarr

The reaction, C_(6)H_(5)ONa +CO_(2)+H_(2)O rarr C_(6)H_(5)OH+NaHCO_(3) suggests that :

Comlete the following reactions : i. C_2 H_5 NH_2 + CHCl_3 + Alc. KOH rarr ii. C_6 H_5 N_2 Cl + H_3 H _3 PO_2 + H_2 O rarr

In the following reaction 'A' is : C_(2)H_(5)MgBr+"epoxyethane" overset(H_(2)O)rarr A

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Multiple Correct
  1. Which of the following reactions are both sterospecific and steroselec...

    Text Solution

    |

  2. Which of the following reactions(s) is/are both non-sterospecific but ...

    Text Solution

    |

  3. Which of the following reactions(s) is/are sterospecific but non-stero...

    Text Solution

    |

  4. Which of the following reaction(s) is/are neither sterospecific nor st...

    Text Solution

    |

  5. The first steps of SN^(1) and SN^(2) recatiosns are, respectively

    Text Solution

    |

  6. Which of the following staements are correct about ElcB reaction ?

    Text Solution

    |

  7. In which fo the following reactions is the correct major product forme...

    Text Solution

    |

  8. Which of the following syntheses could not be doen without involving b...

    Text Solution

    |

  9. Which of the following side chain reaction/s can be used to reduce th...

    Text Solution

    |

  10. In the following reactions: Which of the following staements a...

    Text Solution

    |

  11. Which are the sources of phenol?

    Text Solution

    |

  12. Which contenet (s) of middle oil separate on cooling?

    Text Solution

    |

  13. Sulfanillic acid at pH = 2 and 12 exists as....and migrates towards......

    Text Solution

    |

  14. Consider the following reactions: I. C(2)H(5) - I + NH(3) rarr C(2) ...

    Text Solution

    |

  15. In which of the above reactions does the rate fo SN^(2) reactions dec...

    Text Solution

    |

  16. Consider the folliwng reactions: I. Me(3)C - Br underset(SN^(1))over...

    Text Solution

    |

  17. Which benzene sulphonic acid and p-nitrophenol are treated with NaHCO3...

    Text Solution

    |

  18. The decreasing order of pK(a) value of the folliwng is:

    Text Solution

    |

  19. Among the following, which is/are correct?

    Text Solution

    |

  20. Which of the following will give Hofamann alkene?

    Text Solution

    |