Home
Class 12
CHEMISTRY
Which of the following statements are co...


Which of the following statements are correct?

A

`(I)` and `(II)` are aromatic and have equal basic strength.

B

`(I)` is aromatic, `(II)` is anti-aromatic , but `(II)` is a stronger base than `(I)`.

C

The basically order of above compounds is `(IV) gt (III) gt (II) gt (I)`

D

The conjugate acid of `(IV)` is more stabilised than the conjugate acid of `(II)`.

Text Solution

Verified by Experts

The correct Answer is:
`(c,d)`

In `(IV), the lone piar `oveline(e)'s` of two `N` makes it more basic and does not delocalise in the benzene ring.
In `(III)`, no delocalisationof `overset(..)(N)H_(2) . L.P` of `overset(e)'s`.
In `(II)` no delocalisation of `LP` of overline(e)` on `N`.
In `(I)` delocasation of `LP` of `overline(e)'s` on `N`, via resonance. Hence the order of basic character is: `(IV) gt (III) gt (II) gt (I)`.
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct Answer Type|28 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct|154 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|32 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

Which of the following statements is correct?

Which of the following statements is correct?

Which of the following statements is correct?

Which of the following statements is correct?

Which of the following statements is correct?

Which of the following statements is correct ?

Which of the following statements is correct:

Which of the following statements is correct?

Which of the following statements is correct?