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An orange coloured solution acidified wi...

An orange coloured solution acidified with `H_2SO_4` and treated with a substance `'X'` gives a blue coloured solution of `CrO_5`. The substance `'X'` is

A

`H_(2)O`

B

Dil. HCl

C

`H_(2)O_(2)`

D

Conc. HCl

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the substance 'X' that, when added to an orange-colored solution acidified with H₂SO₄, produces a blue-colored solution of CrO₅. ### Step-by-Step Solution: 1. **Identify the Orange-Colored Solution**: - The orange-colored solution mentioned in the question is likely potassium dichromate (K₂Cr₂O₇). This compound is known for its distinctive orange color. 2. **Acidification with H₂SO₄**: - When potassium dichromate is acidified with sulfuric acid (H₂SO₄), it forms a solution of dichromic acid (H₂Cr₂O₇). The potassium ions (K⁺) are replaced by hydrogen ions (H⁺) from the sulfuric acid. \[ K_2Cr_2O_7 + H_2SO_4 \rightarrow H_2Cr_2O_7 + K_2SO_4 \] 3. **Reaction with Substance 'X'**: - Now, we need to determine what substance 'X' can react with the dichromic acid (H₂Cr₂O₇) to produce CrO₅, which is a blue-colored compound. 4. **Identifying Substance 'X'**: - The only substance among the options provided that can react with H₂Cr₂O₇ to produce CrO₅ is hydrogen peroxide (H₂O₂). The reaction can be represented as follows: \[ H_2Cr_2O_7 + H_2O_2 \rightarrow CrO_5 + H_2O \] 5. **Conclusion**: - Therefore, the substance 'X' that gives a blue-colored solution of CrO₅ when treated with the acidified orange solution is hydrogen peroxide (H₂O₂). ### Final Answer: The substance 'X' is **H₂O₂ (hydrogen peroxide)**. ---
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