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Consider the following reactions I. Al...

Consider the following reactions
I. `AlH_(3)+H^(-)toAlH_(4)^(-)`
II. `H_(2)O+H^(-)toH_(2)+OH^(-)`
Select the correct statement based on these reactions.

A

`H^(-)` is a lewis acid in I and lewis base in II

B

`H^(-)` is a lewis base in I and brosted base in II

C

`H^(-)` is a lewis acid in I and brosted acid in II

D

`H^(-)` is a lewis base in I and II

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given reactions and select the correct statement based on them, we will break down each reaction step by step. ### Step 1: Analyze the first reaction **Reaction I:** \[ \text{AlH}_3 + \text{H}^- \rightarrow \text{AlH}_4^- \] 1. **Identify the species involved:** - \( \text{AlH}_3 \) (Aluminum hydride) contains aluminum, which is in group 13 and has 3 valence electrons. - \( \text{H}^- \) (Hydride ion) has an extra electron, making it a strong reducing agent. 2. **Determine the electron configuration:** - \( \text{AlH}_3 \) has 6 electrons around aluminum (3 from Al and 3 from H), making it electron-deficient and seeking more electrons to complete its octet. 3. **Identify the roles of the species:** - \( \text{AlH}_3 \) acts as a Lewis acid because it can accept electrons. - \( \text{H}^- \) acts as a Lewis base because it donates electrons. 4. **Conclusion for Reaction I:** - The reaction shows that \( \text{H}^- \) donates electrons to \( \text{AlH}_3 \), forming \( \text{AlH}_4^- \). ### Step 2: Analyze the second reaction **Reaction II:** \[ \text{H}_2\text{O} + \text{H}^- \rightarrow \text{H}_2 + \text{OH}^- \] 1. **Identify the species involved:** - \( \text{H}_2\text{O} \) (Water) can act as both an acid and a base. - \( \text{H}^- \) (Hydride ion) is again present. 2. **Determine the roles of the species:** - In this reaction, water donates a proton (H⁺) to \( \text{H}^- \), forming \( \text{H}_2 \) and \( \text{OH}^- \). - Here, \( \text{H}_2\text{O} \) acts as a Bronsted acid (donating H⁺) and \( \text{H}^- \) acts as a Bronsted base (accepting H⁺). 3. **Conclusion for Reaction II:** - The reaction shows that \( \text{H}^- \) accepts a proton from water, resulting in the formation of \( \text{H}_2 \) and \( \text{OH}^- \). ### Final Conclusion: Based on the analysis: - In Reaction I, \( \text{H}^- \) is a Lewis base. - In Reaction II, \( \text{H}^- \) is a Bronsted base. Thus, the correct statement based on these reactions is that \( \text{H}^- \) acts as a Lewis base in the first reaction and a Bronsted base in the second reaction.
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