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Statement-1: Complete hydrolysis of one ...

Statement-1: Complete hydrolysis of one mole of peroxydisulphuric acid gives one mole of `H_(2)O_(2)` and moles of `H_(2)SO_(4)`.
Statement-2: Peroxydisulphuric acid has one peroxy linkage.

A

Statement-1 is true, statement-2 is true, statement-2 is a correct explanation for statement-1

B

Statement-1 is true, statement-2 is true, statement-2 is not correct explanation for statement-1

C

Statement-1 is true, statement-2 is false

D

Statement-1 is false, statement-2 is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding peroxydisulphuric acid (H₂S₂O₈) and its hydrolysis, we will analyze the two statements provided. ### Step-by-Step Solution: 1. **Understanding Peroxydisulphuric Acid**: - Peroxydisulphuric acid has the chemical formula H₂S₂O₈. It contains two sulfur atoms and is characterized by the presence of a peroxy linkage (O-O bond). 2. **Analyzing Statement 1**: - Statement 1 claims that the complete hydrolysis of one mole of peroxydisulphuric acid produces one mole of hydrogen peroxide (H₂O₂) and one mole of sulfuric acid (H₂SO₄). - To verify this, we need to consider the hydrolysis reaction of peroxydisulphuric acid. 3. **Hydrolysis Reaction**: - The hydrolysis of peroxydisulphuric acid can be represented as: \[ \text{H}_2\text{S}_2\text{O}_8 + \text{H}_2\text{O} \rightarrow \text{H}_2\text{SO}_5 + \text{H}_2\text{SO}_4 \] - This reaction shows that one mole of peroxydisulphuric acid reacts with water to produce peroxymonosulphuric acid (H₂SO₅) and sulfuric acid (H₂SO₄), not hydrogen peroxide. 4. **Conclusion for Statement 1**: - Since the hydrolysis does not yield hydrogen peroxide (H₂O₂), Statement 1 is **incorrect**. 5. **Analyzing Statement 2**: - Statement 2 states that peroxydisulphuric acid has one peroxy linkage. - The structure of peroxydisulphuric acid shows that there is indeed an O-O bond, which is the peroxy linkage. 6. **Conclusion for Statement 2**: - Since peroxydisulphuric acid does contain one peroxy linkage, Statement 2 is **correct**. ### Final Evaluation: - Statement 1: **False** - Statement 2: **True** Thus, the correct answer is that Statement 1 is false and Statement 2 is true.
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