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Assertion (A): Aqueous solution of Na(2)...

Assertion (A): Aqueous solution of `Na_(2)CO_(3)` is alkaline in nature.
Reason (R ): when dissolved in water, `Na_(2)CO_(3)` undergoes anionic hydrolysis.

A

Statement-1 is true, statement-2 is true, statement-2 is a correct explanation for statement-1

B

Statement-1 is true, statement-2 is true, statement-2 is not correct explanation for statement-1

C

Statement-1 is true, statement-2 is false

D

Statement-1 is false, statement-2 is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that the aqueous solution of \( \text{Na}_2\text{CO}_3 \) is alkaline in nature. - **Explanation**: Sodium carbonate (\( \text{Na}_2\text{CO}_3 \)) is a salt derived from a strong base (sodium hydroxide, \( \text{NaOH} \)) and a weak acid (carbonic acid, \( \text{H}_2\text{CO}_3 \)). When dissolved in water, it dissociates into sodium ions (\( \text{Na}^+ \)) and carbonate ions (\( \text{CO}_3^{2-} \)). The presence of carbonate ions in solution can lead to an increase in hydroxide ions (\( \text{OH}^- \)), making the solution alkaline. ### Step 2: Understanding the Reason The reason states that when dissolved in water, \( \text{Na}_2\text{CO}_3 \) undergoes anionic hydrolysis. - **Explanation**: When \( \text{Na}_2\text{CO}_3 \) is dissolved in water, the carbonate ions can react with water in a hydrolysis reaction: \[ \text{CO}_3^{2-} + \text{H}_2\text{O} \rightleftharpoons \text{HCO}_3^{-} + \text{OH}^- \] This reaction produces hydroxide ions (\( \text{OH}^- \)), which is characteristic of basic solutions. Since the reaction involves the anion (\( \text{CO}_3^{2-} \)), it is termed anionic hydrolysis. ### Step 3: Conclusion Both the assertion and the reason are true. Furthermore, the reason correctly explains why the assertion is true. ### Final Answer - **Assertion (A)**: True - **Reason (R)**: True - **Conclusion**: The reason is a correct explanation for the assertion.
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