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If silver nitrate solution is added to a...

If silver nitrate solution is added to a salt solution and a yellow precipitate is obtained the salt may contain

A

`Br^(-)`

B

`l^(-)`

C

`Cl^(-)`

D

`F^(-)`

Text Solution

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The correct Answer is:
To solve the question regarding the yellow precipitate formed when silver nitrate solution is added to a salt solution, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: When silver nitrate (AgNO3) is added to a salt solution, it can react with halide ions present in the salt. The halides of interest here are bromide (Br⁻), iodide (I⁻), and fluoride (F⁻). 2. **Identifying the Precipitate**: The yellow precipitate indicates the formation of a silver halide. The relevant reactions are: - Silver bromide (AgBr) forms a yellow precipitate when reacting with bromide ions. - Silver iodide (AgI) also forms a yellow precipitate when reacting with iodide ions. - Silver fluoride (AgF) is colorless in its hydrated form but can appear yellow when dehydrated. 3. **Writing the Chemical Equations**: - For bromide: \[ \text{AgNO}_3 + \text{NaBr} \rightarrow \text{NaNO}_3 + \text{AgBr (yellow precipitate)} \] - For iodide: \[ \text{AgNO}_3 + \text{NaI} \rightarrow \text{NaNO}_3 + \text{AgI (yellow precipitate)} \] - For fluoride (in dehydrated form): \[ \text{AgNO}_3 + \text{NaF} \rightarrow \text{NaNO}_3 + \text{AgF (yellow in anhydrous form)} \] 4. **Conclusion**: Since the yellow precipitate can be formed from either bromide or iodide ions, the salt solution may contain either Br⁻ or I⁻ ions. Additionally, it can also contain F⁻ ions in certain conditions. Therefore, the salt may contain: - Bromide ions (Br⁻) - Iodide ions (I⁻) - Fluoride ions (F⁻) ### Final Answer: The salt may contain bromide (Br⁻), iodide (I⁻), or fluoride (F⁻) ions. ---
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A white sodium salt dissolves in water to give a solution which is neutral to litmus.When silver nitrate solution is added to the solution, a white precipitate is obtained which does not dissolve in dilute HNO_(3) .The anion is

Knowledge Check

  • A white precipitate is formed when silver nitrate is added to a solution containing chloride ions. This precipitate is soluble in Hydrochloric acid ; Nitric acid ; Dilute H 2 S O 4 ; Ammonium hydroxide ;

    A
    Hydrochloric acid
    B
    Nitric acid
    C
    Dilute `H_2SO_4`
    D
    Ammonium hydroxide
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