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Statement-1 : Delta H and Delta U are th...

Statement-1 : `Delta H and Delta U` are the same for the reaction `H_(2)(g) + I_(2)(g) hArr 2 HI(g)`
And
Statement-2 : All reactants and products are in gaseous form.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is Not a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False

D

Statement-1 is False, Statement-2 is True

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding the reaction \( H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \). ### Step-by-step Solution: 1. **Understanding the Reaction:** The reaction involves two moles of gaseous reactants (\( H_2 \) and \( I_2 \)) producing two moles of gaseous product (\( 2 HI \)). 2. **Calculating Change in Moles (\( \Delta n \)):** - The number of moles of products = 2 (from \( 2 HI \)) - The number of moles of reactants = 1 (from \( H_2 \)) + 1 (from \( I_2 \)) = 2 - Therefore, \( \Delta n = \text{moles of products} - \text{moles of reactants} = 2 - 2 = 0 \). 3. **Relating \( \Delta H \) and \( \Delta U \):** - The relationship between enthalpy change (\( \Delta H \)) and internal energy change (\( \Delta U \)) is given by: \[ \Delta H = \Delta U + \Delta n RT \] - Since \( \Delta n = 0 \), the equation simplifies to: \[ \Delta H = \Delta U + 0 \implies \Delta H = \Delta U \] - This confirms that \( \Delta H \) and \( \Delta U \) are indeed the same for this reaction. 4. **Evaluating Statement 1:** - Statement 1 claims that \( \Delta H \) and \( \Delta U \) are the same for the reaction. This is **true** based on our calculations. 5. **Evaluating Statement 2:** - Statement 2 states that all reactants and products are in gaseous form. In this reaction, both \( H_2 \) and \( I_2 \) are gases, and \( 2 HI \) is also a gas. Hence, this statement is also **true**. 6. **Determining the Relationship Between the Statements:** - While both statements are true, Statement 2 does not provide a correct explanation for Statement 1. The equality \( \Delta H = \Delta U \) is derived from the fact that \( \Delta n = 0 \), not merely because all species are gases. ### Final Conclusion: - **Answer:** Both statements are true, but Statement 2 is not a correct explanation for Statement 1. Therefore, the answer is **B**: Statement 1 is true, Statement 2 is true, but Statement 2 is not a correct explanation for Statement 1.
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