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The molal elevation/depression constant ...

The molal elevation/depression constant depends upon -

A

`DeltaH_("solution")`

B

Nature of solvent

C

Nature of solute

D

Freezing point of solution

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The correct Answer is:
To solve the question regarding the factors on which the molal elevation/depression constant depends, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Concept**: - The molal elevation constant (K_b) and the molal depression constant (K_f) are properties that relate to how the boiling point or freezing point of a solvent changes when a solute is added. 2. **Identifying the Relationships**: - The change in freezing point (ΔT_f) can be expressed as: \[ \Delta T_f = K_f \cdot m \] - The change in boiling point (ΔT_b) can be expressed as: \[ \Delta T_b = K_b \cdot m \] - Here, \(m\) is the molality of the solution. 3. **Analyzing the Constants**: - From the equations, we see that K_f and K_b are constants that depend on the solvent used, not on the solute or the specific conditions of the solution. 4. **Evaluating the Options**: - **Option A (ΔH of solution)**: This refers to the enthalpy change when a solute dissolves. It does not affect the molal constants. - **Option B (Nature of solvent)**: This is correct. K_f and K_b depend solely on the solvent. - **Option C (Nature of solute)**: The properties of the solute do not affect K_f or K_b. - **Option D (Freezing point of solution)**: The freezing point itself does not determine the value of K_f. 5. **Conclusion**: - The molal elevation/depression constant depends only on the nature of the solvent. Therefore, the correct answer is **Option B: Nature of solvent**. ### Final Answer: The molal elevation/depression constant depends upon the **nature of solvent**.
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