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van't Hoff factor for SrCl(2) at 0.01 M ...

van't Hoff factor for `SrCl_(2)` at 0.01 M is 1.6. Percent dissociation of `SrCl_(2)` is

A

70

B

55

C

40

D

30

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The correct Answer is:
To find the percent dissociation of \( \text{SrCl}_2 \) given its van't Hoff factor \( i \) at 0.01 M is 1.6, we can follow these steps: ### Step 1: Understand the dissociation of \( \text{SrCl}_2 \) The dissociation of \( \text{SrCl}_2 \) can be represented as: \[ \text{SrCl}_2 \rightarrow \text{Sr}^{2+} + 2 \text{Cl}^- \] From this equation, we can see that one formula unit of \( \text{SrCl}_2 \) produces 3 ions in total (1 \( \text{Sr}^{2+} \) ion and 2 \( \text{Cl}^- \) ions). ### Step 2: Define the variables Let: - \( n \) = number of particles produced upon dissociation = 3 (from the dissociation equation) - \( \alpha \) = percent dissociation (expressed as a fraction) ### Step 3: Use the van't Hoff factor formula The van't Hoff factor \( i \) is given by the formula: \[ i = 1 + (n - 1) \alpha \] Substituting the known values: \[ 1.6 = 1 + (3 - 1) \alpha \] ### Step 4: Simplify the equation This simplifies to: \[ 1.6 = 1 + 2\alpha \] Subtract 1 from both sides: \[ 0.6 = 2\alpha \] ### Step 5: Solve for \( \alpha \) Now, divide both sides by 2: \[ \alpha = \frac{0.6}{2} = 0.3 \] ### Step 6: Convert \( \alpha \) to percent dissociation To find the percent dissociation, multiply \( \alpha \) by 100: \[ \text{Percent dissociation} = 0.3 \times 100 = 30\% \] ### Final Answer The percent dissociation of \( \text{SrCl}_2 \) is **30%**. ---
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