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Name the type of isomerism exibited by t...

Name the type of isomerism exibited by the following isomers :
(1) `[Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)]`
(2) `[Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O`
(3) `[Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2)`
(4) `[Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)`

Text Solution

AI Generated Solution

To determine the type of isomerism exhibited by the given isomers, we will analyze each pair step by step. ### Step 1: Analyzing the first pair **Isomers:** `[Cr(NH₃)₆][Cr(CN)₆]` and `[Cr(NH₃)₄(CN)₂][Cr(NH₃)₂(CN)₄]` **Analysis:** In this case, we observe that the ligands have exchanged their positions between two different coordination complexes. This indicates that the isomers differ in the arrangement of ligands around the metal centers. ...
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