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Which reagent can be used to identify Ni...

Which reagent can be used to identify `Ni^(2+)` ion ?

A

Resorcinol

B

Dimethyl glyoxime

C

Diphenyl benzidine

D

Potassium ferrocyanide

Text Solution

AI Generated Solution

The correct Answer is:
To identify the `Ni^(2+)` ion, we can use the following steps: ### Step-by-Step Solution: 1. **Understanding the Question**: We need to identify which reagent can be used to detect the presence of nickel ions (`Ni^(2+)`). 2. **Reviewing the Options**: The options provided are: - Option 1: Resorcinol - Option 2: Dimethylglyoxane (DMG) - Option 3: Diphenylbenzidine - Option 4: Potassium ferrocyanide 3. **Identifying the Correct Reagent**: - Among the options, **Dimethylglyoxane (DMG)** is known to react with nickel ions. - When nickel salts (like NiCl2) react with dimethylglyoxane in the presence of ammonium hydroxide (NH4OH), they form a scarlet red precipitate of nickel dimethylglyoxane. 4. **Chemical Reaction**: The reaction can be summarized as follows: - **Reactants**: NiCl2 + 2 DMG + 2 NH4OH - **Products**: Nickel dimethylglyoxane (scarlet red precipitate) + 2 NH4Cl + Water 5. **Conclusion**: Based on the reaction, we conclude that the reagent used to identify `Ni^(2+)` ion is **Dimethylglyoxane (DMG)**. Therefore, the correct answer is **Option 2**.
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