Home
Class 12
CHEMISTRY
Classify each of the following complexes...

Classify each of the following complexes as either high or low spin . Explain your answers.
(i) `[Co(H_(2)O)_(6)]^(2+) mu= 3.87 B.M. " " [Co(CN)_(6)]^(3-) mu=0.0 B.M.`
(ii) `[Fe(NO_(2))_(6)]^(4-) mu=0.0 B.M." "[Fe(H_(2)O)_(6)]^(3+) mu =5.94 B.M. `

Text Solution

AI Generated Solution

To classify the given complexes as high spin or low spin, we need to analyze the magnetic moments provided and the electronic configurations of the metal ions in each complex. ### Step-by-Step Solution: **(i) Complex: \([Co(H_2O)_6]^{2+}\)** 1. **Determine the oxidation state of cobalt**: - In \([Co(H_2O)_6]^{2+}\), cobalt is in the +2 oxidation state. ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section-J Aakash Challenger Questions )|10 Videos
  • COORDINATION COMPOUNDS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section-H Multiple True-False Type Questions )|5 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section - J Aakash Challengers Questions)|6 Videos
  • ELECTROCHEMISTRY

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION - J) (Aakash Challengers Questions)|10 Videos

Similar Questions

Explore conceptually related problems

[Co(H_(2)O)_(6)]^(3+) complex is

Select incorrect match for [M(H_(2)O)_(6)]^(2+) complex.

[Fe(H_(2)O)_(6)]^(3+) and [Fe(CN)_(6)]^(3-) differ in

Arrange the following complexes in order of increasing crystal field splitting . [Fe(H_(2)O)_(6)]^(2+),[Fe(H_(2)O)_(6)]^(3+) , [FeCl_(6)]^(4-) .

[Fe(H_(2)O)_(6)]^(2+) and [Fe(CN)_(6)]^(4-) differ in :

[Fe(H_(2)O)_(6)]^(2+) and [Fe(CN)_(6)]^(4-) differ in :

Which complex of the following pairs has the larger value of Delta_(0) (i) [Co(CN)_(6)]^(3-) and [Co(NH_(3))_(6)]^(3+) (ii) [Co(NH_(3))_(6)]^(3+) and [CoF_(6)]^(3-) (iii) [Co(H_(2)O)_(6)]^(2+) and [Co(H_(2)O)_(6)]^(3+) .

Calculate magnetic moment of Fe^(3+) in [Fe(CN)_(6)]^(3+) and in [Fe(H_(2)O)_(6)]^(3+)

Explain the following giving reasons [Fe(H_(2)O)_(6)]^(3+) ion is more paramagnetic than [Fe(CN)_(6)]^(3-) ion

Which of the following complexes has more Delta_O vlaue and why? (i) Fe(H_2O)_6]^(3+) and (ii) [Fe(CN)_6]^(3-) . Also find the number of unpared electrons in them.