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Which among the following is a meta dire...

Which among the following is a meta directing group?

A

`-CH_(3)`

B

`-underset(O)underset(||)overset(O)overset(||)(S)-O-H`

C

`-O-CH_(3)`

D

`-NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which among the given options is a meta directing group, we need to analyze each option based on their electronic effects on a benzene ring. Meta directing groups are those that increase the electron density at the meta position of the benzene ring. ### Step-by-Step Solution: 1. **Understanding Meta Directing Groups**: - Meta directing groups are substituents that, when attached to a benzene ring, direct incoming electrophiles to the meta position relative to themselves. They typically withdraw electron density from the ring. 2. **Analyzing Each Option**: - **Option 1: CH3 (Methyl Group)**: - The methyl group (CH3) is an electron-donating group (due to +I effect). It increases electron density at the ortho and para positions, thus making it an ortho-para directing group, not a meta directing group. - **Option 2: SO3H (Sulfonic Acid Group)**: - The sulfonic acid group (SO3H) is an electron-withdrawing group due to the presence of electronegative oxygen atoms. It decreases electron density at the ortho and para positions, while increasing it at the meta position. Therefore, this is a meta directing group. - **Option 3: OCH3 (Methoxy Group)**: - The methoxy group (OCH3) is an electron-donating group due to resonance (+R effect). It increases electron density at the ortho and para positions, making it an ortho-para directing group, not a meta directing group. - **Option 4: NH2 (Amino Group)**: - The amino group (NH2) is also an electron-donating group due to resonance (+R effect). It increases electron density at the ortho and para positions, making it an ortho-para directing group, not a meta directing group. 3. **Conclusion**: - After analyzing all the options, we find that the only meta directing group among the given options is **SO3H**. ### Final Answer: **SO3H is a meta directing group.**
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AAKASH INSTITUTE ENGLISH-HYDROCARBONS-ASSIGNMENT SECTION-A COMPETITION LEVEL DIFFER BY
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