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CH(3)-C-=CHunderset("catalyst")overset("...

`CH_(3)-C-=CHunderset("catalyst")overset("Linddar's")rarr(A)underset(H_(2)O)overset("Conc"H_(2)SO_(4))rarr(B)`
What are the products (A) and (B) in the given reaction?

A

`CH_(3)-CH=CH_(2), CH_(3)-underset(OH)underset(|)(CH)-CH_(3)`

B

`CH_(2)=CH-CH_(3),CH_(3)-underset(OH)underset(|)(CH)-CH_(3)`

C

`CH_(2)=CH-CH_(3).CH_(3)-C-=CH`

D

`CH_(3)-CH=CH_(2).CH_(3)-underset(OSO_(2)OH)underset(|)(CH)-CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the given reaction involving propyne (CH₃-C≡CH) and its subsequent reactions. ### Step 1: Identify the starting compound The starting compound is propyne, which has the structure: \[ \text{CH}_3-\text{C} \equiv \text{C}\text{H} \] ### Step 2: Reaction with Lindlar's Catalyst Propyne reacts with Lindlar's catalyst. Lindlar's catalyst is a palladium catalyst that is poisoned to selectively reduce alkynes to cis-alkenes. The reaction can be represented as: \[ \text{CH}_3-\text{C} \equiv \text{C}\text{H} \xrightarrow{\text{Lindlar's catalyst}} \text{CH}_3-\text{C}=\text{CH}_2 \] The product (A) formed is **propene (CH₃-CH=CH₂)**. ### Step 3: Reaction with Concentrated H₂SO₄ and Water Next, the product propene (A) undergoes hydrolysis in the presence of concentrated sulfuric acid (H₂SO₄) and water (H₂O). The mechanism involves the formation of a carbocation intermediate: 1. The concentrated H₂SO₄ donates a proton (H⁺) to propene, forming a carbocation: \[ \text{CH}_3-\text{C}=\text{CH}_2 + \text{H}^+ \rightarrow \text{CH}_3-\text{C}^+(\text{H})-\text{CH}_2 \] 2. The carbocation is then attacked by water (H₂O), leading to the formation of an alcohol: \[ \text{CH}_3-\text{C}^+(\text{H})-\text{CH}_2 + \text{H}_2\text{O} \rightarrow \text{CH}_3-\text{C}(\text{OH})(\text{H})-\text{CH}_3 \] The product (B) formed is **2-propanol (CH₃-CHOH-CH₃)**. ### Summary of Products - Product (A) is **propene (CH₃-CH=CH₂)**. - Product (B) is **2-propanol (CH₃-CHOH-CH₃)**. ### Final Answer - A: Propene (CH₃-CH=CH₂) - B: 2-Propanol (CH₃-CHOH-CH₃) ---
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