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Which one of the following compounds can...

Which one of the following compounds can be used to distinguish propane from propene?

A

Aqueous `KMnO_(4)`

B

Dil `H_(2)SO_(4)`

C

`Br_(2)-H_(2)O`

D

Ammonical `AgNO_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound can be used to distinguish propane from propene, we can follow these steps: ### Step 1: Identify the Compounds - Propane (C3H8) is an alkane with single bonds. - Propene (C3H6) is an alkene with a double bond. ### Step 2: Understand the Reactivity - Alkenes (like propene) can undergo reactions due to the presence of a double bond. - Alkanes (like propane) do not react in the same way because they lack double bonds. ### Step 3: Analyze the Given Compounds 1. **Aqueous KMnO4 (cold and dilute)**: This is a reagent that can oxidize alkenes. When propene reacts with KMnO4, it will oxidize and produce a brown precipitate of MnO2, indicating the presence of a double bond. Propane will not react, and the purple color of KMnO4 will remain unchanged. 2. **Dilute H2SO4**: This will not specifically distinguish between propane and propene as both can react under certain conditions, but it is not a definitive test. 3. **Bromine Water**: This can also distinguish between alkenes and alkanes. Propene will decolorize bromine water due to the addition reaction across the double bond, while propane will not. 4. **Ammoniacal Silver Nitrate**: This is typically used to test for alkynes (triple bonds) and does not provide a clear distinction between propane and propene. ### Step 4: Conclusion The best reagents to distinguish propane from propene are **Aqueous KMnO4** and **Bromine Water**. However, since the question asks for one compound, we can conclude that **Aqueous KMnO4** is the most definitive answer because it gives a clear visual change (brown precipitate) when reacting with propene but not with propane. ### Final Answer **Aqueous KMnO4 (cold and dilute)** can be used to distinguish propane from propene. ---
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