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(CH(3))(3) CMgCl on reaction with D(2)O ...

`(CH_(3))_(3) CMgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3)CD`

B

`(CH_(3))_(3)COD`

C

`(CD_(3))_(3)CD`

D

`(CD_(3))_(3)CD`

Text Solution

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The correct Answer is:
To solve the problem of what `(CH₃)₃C MgCl` produces when it reacts with `D₂O`, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are `(CH₃)₃C MgCl` (tert-butyl magnesium chloride) and `D₂O` (deuterated water). ### Step 2: Understand the Mechanism In this reaction, the carbon-magnesium bond in `(CH₃)₃C MgCl` is nucleophilic. The carbon atom bonded to magnesium has a strong tendency to donate its electron pair to a positively charged region, which in this case is the deuterium atom in `D₂O`. ### Step 3: Reaction Process 1. The carbon atom in `(CH₃)₃C MgCl` donates its electron pair to a deuterium atom from `D₂O`. 2. This results in the formation of a new bond between the carbon and deuterium, creating `(CH₃)₃C-D`. 3. The remaining part of `D₂O` (which is `OD`) will combine with `MgCl` to form `MgClOH`. ### Step 4: Write the Reaction The overall reaction can be represented as: \[ (CH₃)₃C MgCl + D₂O \rightarrow (CH₃)₃C-D + MgClOH \] ### Step 5: Identify the Products From the reaction, we can see that the primary product is `(CH₃)₃C-D`, which is tert-butyl deuteride. ### Final Answer The product of the reaction `(CH₃)₃C MgCl` with `D₂O` is `(CH₃)₃C-D`. ---
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Consider the following reactions I. II. (CH_(3))_(2) underset(OH)underset(|)(C ) - CH_(2) - CHO overset(Delta)(to) III. (CH_(3))_(2) CHCH_(2) - underset(F)underset(|)(C )H - CH_(3) underset(Delta)overset(CH_(3)O^(-)Na^(+))(to) IV. (CH_(3))_(2) CH - underset(Br)underset(|)(C )H - CH_(3) overset((CH_(3))_(3) CO^(-) k^(+))(to) Which of these reaction will not produce Hoffmann product?

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In how many reactions CO_(2) gas is released out after reaction with NaHCO_(3) (1) CH_(3)-underset(O)underset(||)overset(O)overset(||)(S)-O-H+NaHCO_(3) rarr (2) CH_(3)-underset(O)underset(||)(C)-O-H+NaHCO_(3) rarr CH_(3)-CH_(2)-OH+NaHCO_(3) rarr (5) CH_(3)-C-=C-H+NaHCO_(3) rarr

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