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HBr reacts with CH(2)=CH-OCH(3) under an...

`HBr` reacts with `CH_(2)=CH-OCH_(3)` under anhydrous conditions at room temperature to give?

A

`CH_(3)CHO` and `CH_(3)OH`

B

`BrCH_(2)CHO` and `CH_(3)OH`

C

`BrCH_(2)-CH_(2)-O-CH_(2)`

D

`H_(3)C-CHBr-OCH_(3)`

Text Solution

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To solve the problem of what happens when HBr reacts with methyl vinyl ether (CH₂=CH-OCH₃) under anhydrous conditions at room temperature, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - HBr (Hydrobromic acid) - Methyl vinyl ether (CH₂=CH-OCH₃) ### Step 2: Understand the Reaction Type The reaction between HBr and methyl vinyl ether is an electrophilic addition reaction. In this reaction, the double bond in the vinyl ether will react with HBr. ### Step 3: Electrophilic Attack In the presence of HBr, the double bond (C=C) in methyl vinyl ether will undergo an electrophilic attack. The H⁺ from HBr will add to one of the carbon atoms in the double bond, forming a carbocation. ### Step 4: Carbocation Formation When H⁺ adds to the carbon atom, we can have two possible carbocations: 1. If H⁺ adds to the terminal carbon (CH₂), a primary carbocation is formed. 2. If H⁺ adds to the internal carbon (CH), a more stable secondary carbocation is formed. In this case, the more stable secondary carbocation will be favored due to its stability. ### Step 5: Nucleophilic Attack After the formation of the carbocation, the Br⁻ ion from HBr will act as a nucleophile and attack the positively charged carbon atom of the carbocation. ### Step 6: Product Formation The final product of the reaction will be: - The addition of Br to the carbon that was positively charged. - The ether group (OCH₃) remains attached to the other carbon. Thus, the product formed is: **CH₃-CH(Br)-OCH₃** (2-bromo-1-methoxyethane) ### Final Answer The reaction of HBr with methyl vinyl ether (CH₂=CH-OCH₃) under anhydrous conditions at room temperature yields **2-bromo-1-methoxyethane (CH₃-CH(Br)-OCH₃)**. ---
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AAKASH INSTITUTE ENGLISH-HYDROCARBONS-SECTION-B OBJECTIVE TYPE QUESTIONS (ONE OPTION IS CORRECT)
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  2. In the given reaction CH(3)-overset(O)overset(||)(C)-C(2)H(5)overset...

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  3. The most suitable sequence of reagents to perform this conversion is

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  4. The compound having only primary hydrogen atoms is

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  5. Which equation does not represent an example of Friedal-crafts reactio...

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  6. In the reactions underset(CH2)overset(CH2)(||)underset"acid"overset"H...

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  7. Arrange the following compounds in increasing order of reactivity towa...

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  8. Among the following compounds, the decreasing order of reactivity towa...

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  9. The alkene formed as a major product in the above elimination reaction...

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  10. HBr reacts with CH(2)=CH-OCH(3) under anhydrous conditions at room tem...

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  11. Colouration of Br(2)//C Cl(4) will be discharged by

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  12. underset(Br)underset(|)(CH(2))-CH=CH-underset(Br)underset(|)(CH(2))ove...

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  13. The ozonolysis product is

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  14. Consider the following reaction The reactive intermediate invovled ...

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  15. Reaction of HBr with propene in the presence of peroxide gives :-

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  16. Which of the following compound is most reactive towards an electrophi...

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  17. The reaction is : CH(3)CHBr-CH(2)Br+2KOH("alc.")overset(Delta)rarr C...

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  18. Which of the following alkene in acid catalysed hydration form 2-methy...

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  19. The reaction of chlorine water with propene gives

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  20. Point out A in the given reaction sequence Aoverset(O(3)//H(2)O(2))r...

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