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underset(Br)underset(|)(CH(2))-CH=CH-und...

`underset(Br)underset(|)(CH_(2))-CH=CH-underset(Br)underset(|)(CH_(2))overset(Zn / CH_(3)OH)rarr` Product The predominating product is

A

B

`CH_(2)=C=C=CH_(2)`

C

`CH_(2)=CH-CH=CH_(2)`

D

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given compound and the reagents involved in the reaction. ### Step-by-Step Solution: 1. **Identify the Structure of the Compound**: The compound provided is a 1,4-dibromobut-2-ene. Its structure can be represented as: \[ \text{Br-CH}_2-\text{CH}=\text{CH-CH}_2-\text{Br} \] Here, two bromine atoms are attached to the terminal carbon atoms of the butene chain. 2. **Understand the Reagents**: The reagents given are zinc (Zn) and methanol (CH₃OH). Zinc is known to facilitate dehalogenation reactions, which means it can remove halogen atoms from organic compounds. 3. **Reaction Mechanism**: - When zinc reacts with the dibromide, it will remove the two bromine atoms. This process is called dehalogenation. - The removal of the bromine atoms leads to the formation of a double bond between the adjacent carbon atoms, resulting in the formation of a radical intermediate. 4. **Formation of the Product**: - The radical intermediate can undergo a rearrangement or recombination to form a cyclic structure due to the proximity of the carbon atoms. - Specifically, the two carbon atoms that were initially bonded to the bromines can form a cyclobutene structure as they come together to stabilize the radical. 5. **Final Product**: The predominant product of the reaction is cyclobutene, which can be represented as: \[ \text{C}_4\text{H}_6 \quad (\text{cyclobutene}) \] ### Conclusion: The major product formed from the reaction of 1,4-dibromobut-2-ene with zinc in methanol is cyclobutene. ---
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AAKASH INSTITUTE ENGLISH-HYDROCARBONS-SECTION-B OBJECTIVE TYPE QUESTIONS (ONE OPTION IS CORRECT)
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