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The reaction is : CH(3)CHBr-CH(2)Br+2K...

The reaction is `:`
`CH_(3)CHBr-CH_(2)Br+2KOH("alc.")overset(Delta)rarr CH_(3)-C equiv CH+2KBr+2H_(2)O`

A

Dehalogenation

B

Dehydrohalogenation

C

Decarboxytation

D

Dehydration

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction, we need to analyze the transformation of the reactant into the product and identify the type of reaction taking place. Here’s a step-by-step breakdown: ### Step 1: Identify the Reactant and Product The reactant is `CH₃CHBrCH₂Br`, which has two bromine atoms attached to adjacent carbon atoms. The product is `CH₃C≡CH`, which is an alkyne with a triple bond between the second and third carbon atoms. ### Step 2: Understand the Role of KOH (alc.) The presence of alcoholic KOH indicates that this is a dehydrohalogenation reaction. Alcoholic KOH is a strong base that facilitates the elimination of halogen atoms and hydrogen atoms from the carbon chain. ### Step 3: Mechanism of the Reaction 1. **First Elimination**: The first step involves the removal of one bromine atom (Br) from the carbon chain and a hydrogen atom (H) from the adjacent carbon. This results in the formation of a double bond (alkene). - From `CH₃CHBrCH₂Br`, remove one `Br` and one `H`, leading to the formation of `CH₃C=CHBr`. 2. **Second Elimination**: In the second step, the remaining bromine atom (Br) is eliminated along with another hydrogen atom (H) from the adjacent carbon, resulting in the formation of a triple bond (alkyne). - From `CH₃C=CHBr`, remove the second `Br` and `H`, yielding `CH₃C≡CH`. ### Step 4: Final Products After both eliminations, the final products are: - `CH₃C≡CH` (the alkyne) - `2KBr` (from the two bromine atoms) - `2H₂O` (from the hydroxide ions reacting with the eliminated hydrogen atoms) ### Conclusion The overall reaction can be summarized as: \[ CH₃CHBrCH₂Br + 2KOH \text{(alc.)} \xrightarrow{\Delta} CH₃C≡CH + 2KBr + 2H₂O \] ### Type of Reaction This reaction is classified as **dehydrohalogenation** because it involves the removal of hydrogen and halogen atoms from the reactant. ---
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AAKASH INSTITUTE ENGLISH-HYDROCARBONS-SECTION-B OBJECTIVE TYPE QUESTIONS (ONE OPTION IS CORRECT)
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